Biotransformation of (+)-camphor by cultured cells of Eucalyptus perriniana.

Abstract:

:Seven new biotransformation products were isolated from a jar fermentor culture of Eucalyptus perriniana following administration of (+)-camphor. The main product was (1S,4R,6S)-6-hydroxybornan-2-one 6-O-beta-D-glucopyranoside. The minor components were (1S,4R,6R)-6-hydroxybornan-2-one 6-O-beta-D-glucopyranoside, (1R,4S,6S)-6-hydroxybornan-2-one 6-O-beta-D-glucopyranoside, (1R,4R,5R)-5-hydroxybornan-2-one 5-O-beta-D-glucopyranoside, (1R,3R,4S)-3-hydroxybornan-2-one 3-O-beta-D-glucopyranoside, (1R,4R,7R)-8-hydroxybornan-2-one 8-O-beta-D-glucopyranoside and 2-(4-oxo-2,2,3-trimethylcyclopentyl)-ethyl-beta-D-glucopyranoside. All products were mono-glucosides and the oxygen function was introduced before glucosylation. Reduction of the ketone group of camphor was not observed.

journal_name

Phytochemistry

journal_title

Phytochemistry

authors

Orihara Y,Noguchi T,Furuya T

doi

10.1016/s0031-9422(00)90643-5

subject

Has Abstract

pub_date

1994-03-01 00:00:00

pages

941-5

issue

4

eissn

0031-9422

issn

1873-3700

pii

S0031-9422(00)90643-5

journal_volume

35

pub_type

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