Abstract:
:A method is described for the enrichment of odd very-long-chain polyunsaturated fatty acids (VLCPUFAs) by means of RP-HPLC and argentation TLC from total fatty acids of the dinoflagellate A. carterae and their identification as picolinyl esters by means of microbore liquid chromatography-mass spectrometry with atmospheric pressure chemical ionization (LC-MS/APCI). The combination of argentation TLC and LC-MS/APCI was used to identify rare and unusual odd VLCPUFAs up to nonacosahexaenoic acid. Two acids, (allZ)-nonacosa-11,14,17,20,23-pentaenoic acid (29:5n-6) and (allZ)-nonacosa-11,14,17,20,23,26-hexaenoic acid (29:6n-3), were synthesized for the first time to unambiguously confirm their structure. Possible biosynthetic pathways for odd VLCPUFAs are also proposed.
journal_name
Phytochemistryjournal_title
Phytochemistryauthors
Rezanka T,Nedbalová L,Sigler Kdoi
10.1016/j.phytochem.2008.08.021subject
Has Abstractpub_date
2008-11-01 00:00:00pages
2849-55issue
16eissn
0031-9422issn
1873-3700pii
S0031-9422(08)00404-4journal_volume
69pub_type
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