Enhancement effect of hematite nanoparticles on fermentative hydrogen production.

Abstract:

:The effects of hematite nanoparticles concentration (0-1600 mg/L) and initial pH (4.0-10.0) on hydrogen production were investigated in batch assays using sucrose-fed anaerobic mixed bacteria at 35°C. The optimum hematite nanoparticles concentration with an initial pH 8.48 was 200mg/L, with the maximum hydrogen yield of 3.21 mol H(2)/mol sucrose which was 32.64% higher than the blank test. At 200mg/L hematite nanoparticles concentration, further initial pH optimization experiments indicated that at pH 6.0 the maximum hydrogen yield reached to 3.57 mol H(2)/mol sucrose and hydrogen content was 66.1%. The slow release of hematite nanoparticles had been recorded by transmission electron microscopy (TEM). In addition, TEM analysis indicated that the hematite nanoparticles can affect the shape of bacteria, namely, its length increased from ca. 2.0-3.6 μm to ca. 2.6-5.6 μm, and width became narrower.

journal_name

Bioresour Technol

journal_title

Bioresource technology

authors

Han H,Cui M,Wei L,Yang H,Shen J

doi

10.1016/j.biortech.2011.05.089

subject

Has Abstract

pub_date

2011-09-01 00:00:00

pages

7903-9

issue

17

eissn

0960-8524

issn

1873-2976

pii

S0960-8524(11)00796-6

journal_volume

102

pub_type

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