Abstract:
:This is the first of two papers concerning the behavior of black liquor during pyrolysis under pressurized conditions. Two industrial kraft liquors were pyrolyzed in a laboratory-scale pressurized single particle reactor and a pressurized grid heater at temperatures ranging from 650 to 1100 degrees C and at pressures between 1 and 20 bar. The dimensions of the chars produced were measured and the specific swollen volume was calculated. Swelling decreased roughly logarithmically over the pressure range 1-20 r. An expression is developed to predict the specific swollen volume at elevated pressure when the volume at 1 bar is known. The bulk density of the char increased with pressure, indicating that liquors will be entrained less easily at higher pressures.
journal_name
Bioresour Technoljournal_title
Bioresource technologyauthors
Whitty K,Backman R,Hupa Mdoi
10.1016/j.biortech.2006.11.065subject
Has Abstractpub_date
2008-02-01 00:00:00pages
663-70issue
3eissn
0960-8524issn
1873-2976pii
S0960-8524(07)00053-3journal_volume
99pub_type
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