The catalytic activity enhancement and biodegradation potential of free laccase and novel sol-gel laccase in non-conventional solvents.

Abstract:

:The catalytic activity of free laccase and a novel sol-gel laccase (SOLAC) in ionic liquids and organic solvents was demonstrated by using 2,6-dimethoxyphenol (2,6-DMP) as a substrate. The enhancement of the catalytic activity of the SOLAC was observed and compared to the free laccase in both media. The oxidative biodegradation of o-chlorophenol as a model of phenolic environmental pollutants in organic media shows that the degradation was observed only when using water pre-saturated organic solvents or reverse micelle system. The SOLAC gave higher biodegradation rate in either aqueous or organic solvents, in which the optimum temperature was observed at 40 °C for the reverse micelle system as a reaction medium. All results demonstrated the potential use of the SOLAC for biodegradation of phenolic environmental pollutants in non-conventional media.

journal_name

Bioresour Technol

journal_title

Bioresource technology

authors

Mohidem NA,Mat HB

doi

10.1016/j.biortech.2012.02.138

subject

Has Abstract

pub_date

2012-06-01 00:00:00

pages

472-7

eissn

0960-8524

issn

1873-2976

pii

S0960-8524(12)00406-3

journal_volume

114

pub_type

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