Abstract:
:Co-naphthalocyanine (CoNPc) was prepared by heat treatment for cathode catalysts to be used in microbial fuel cells (MFCs). Four different catalysts (Carbon black, NPc/C, CoNPc/C, Pt/C) were compared and characterized using XPS, EDAX and TEM. The electrochemical characteristics of oxygen reduction reaction (ORR) were compared by cyclic voltammetry (CV) and linear sweep voltammetry (LSV). The Co-macrocyclic complex improves the catalyst dispersion and oxygen reduction reaction of CoNPc/C. The maximum power of CoNPc/C was 64.7 mW/m(2) at 0.25 mA as compared with 81.3 mW/m(2) of Pt/C, 29.7 mW/m(2) of NPc/C and 9.3 mW/m(2) of carbon black when the cathodes were implemented in H-type MFCs. The steady state cell, cathode and anode potential of MFC with using CoNPc/C were comparable to those of Pt/C.
journal_name
Bioresour Technoljournal_title
Bioresource technologyauthors
Kim JR,Kim JY,Han SB,Park KW,Saratale GD,Oh SEdoi
10.1016/j.biortech.2010.07.005subject
Has Abstractpub_date
2011-01-01 00:00:00pages
342-7issue
1eissn
0960-8524issn
1873-2976pii
S0960-8524(10)01192-2journal_volume
102pub_type
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