Liquefaction of cornstalk in hot-compressed phenol-water medium to phenolic feedstock for the synthesis of phenol-formaldehyde resin.

Abstract:

:Cornstalk powders were effectively liquefied in a hot-compressed phenol-water medium (1:4 wt/wt). The optimum liquefaction temperature was around 350 degrees C, where the liquid yield attained a maximum at about 70 wt%. The addition of sodium carbonate showed negligible effect over the Liquefaction product yields. When liquefied in phenol-water medium, essentially no phenol was combined with the liquid products, and the cornstalk-derived bio-oils were partially degraded monomeric and oligomeric products with a broad molecular distribution. Resol type bio-based phenol formaldehyde resins were readily synthesized from the cornstalk-derived bio-oils catalyzed by sodium hydroxide.

journal_name

Bioresour Technol

journal_title

Bioresource technology

authors

Wang M,Xu CC,Leitch M

doi

10.1016/j.biortech.2008.10.043

subject

Has Abstract

pub_date

2009-04-01 00:00:00

pages

2305-7

issue

7

eissn

0960-8524

issn

1873-2976

pii

S0960-8524(08)00919-X

journal_volume

100

pub_type

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