A kinetic model for hydrothermal pretreatment of sugarcane straw.

Abstract:

:This work presents kinetic models of cellulose and hemicellulose extraction during hydrothermal pretreatment of sugarcane straw. Biomass was treated under conditions of 180, 195, and 210°C, using a solid/liquid ratio of 1:10 (w/v). In this study, cellobiose, glucose, formic acid and hydroxymethylfurfural (from cellulosic fraction) and xylose, arabinose, acetic acid, glucuronic acid and furfural (from hemicellulosic fraction) were taken into account in the kinetic parameters determination. The global search algorithm Simulated Annealing was used to fit the models. At 195°C/15min, 85% of hemicellulose and 21% of cellulose removal was reached. For the confidence regions, it was observed that it can be broad, which is coherent with the fact that the parameters are highly correlated. Kinetic models proposed for both cellulosic and hemicellulosic fractions degradation fitted well to the experimental data.

journal_name

Bioresour Technol

journal_title

Bioresource technology

authors

Dos Santos Rocha MSR,Pratto B,de Sousa R Júnior,Almeida RMRG,Cruz AJGD

doi

10.1016/j.biortech.2016.12.087

subject

Has Abstract

pub_date

2017-03-01 00:00:00

pages

176-185

eissn

0960-8524

issn

1873-2976

pii

S0960-8524(16)31765-5

journal_volume

228

pub_type

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