Diatomite derived hierarchical hybrid anode for high performance all-solid-state lithium metal batteries.

Abstract:

:Lithium metal based anode with hierarchical structure to enable high rate capability, volume change accommodation, and dendritic suppression is highly desirable for all-solid-state lithium metal battery. However, the fabrication of hierarchical lithium metal based anode is challenging due to the volatility of lithium. Here, we report that natural diatomite can act as an excellent template for constructing hierarchical silicon-lithium based hybrid anode for high performance all-solid-state lithium metal battery. This hybrid anode exhibits stable lithium stripping/plating performance over 1000 h with average overpotential lower than 100 mV without any short circuit. Moreover, all-solid-state full cell using this lithium metal composite anode to couple with lithium iron phosphate cathode shows excellent cycling stability (0.04% capacity decay rate for 500 cycles at 0.5C) and high rate capability (65 mAh g-1 at 5C). The present natural diatomite derived hybrid anode could further promote the fabrication of high performance all-solid-state lithium batteries from sustainable natural resources.

journal_name

Nat Commun

journal_title

Nature communications

authors

Zhou F,Li Z,Lu YY,Shen B,Guan Y,Wang XX,Yin YC,Zhu BS,Lu LL,Ni Y,Cui Y,Yao HB,Yu SH

doi

10.1038/s41467-019-10473-w

subject

Has Abstract

pub_date

2019-06-06 00:00:00

pages

2482

issue

1

issn

2041-1723

pii

10.1038/s41467-019-10473-w

journal_volume

10

pub_type

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