Fast kinetics of multivalent intercalation chemistry enabled by solvated magnesium-ions into self-established metallic layered materials.

Abstract:

:Rechargeable magnesium batteries are one of the most promising candidates for next-generation battery technologies. Despite recent significant progress in the development of efficient electrolytes, an on-going challenge for realization of rechargeable magnesium batteries remains to overcome the sluggish kinetics caused by the strong interaction between double charged magnesium-ions and the intercalation host. Herein, we report that a magnesium battery chemistry with fast intercalation kinetics in the layered molybdenum disulfide structures can be enabled by using solvated magnesium-ions ([Mg(DME)x]2+). Our study demonstrates that the high charge density of magnesium-ion may be mitigated through dimethoxyethane solvation, which avoids the sluggish desolvation process at the cathode-electrolyte interfaces and reduces the trapping force of the cathode lattice to the cations, facilitating magnesium-ion diffusion. The concept of using solvation effect could be a general and effective route to tackle the sluggish intercalation kinetics of magnesium-ions, which can potentially be extended to other host structures.

journal_name

Nat Commun

journal_title

Nature communications

authors

Li Z,Mu X,Zhao-Karger Z,Diemant T,Behm RJ,Kübel C,Fichtner M

doi

10.1038/s41467-018-07484-4

subject

Has Abstract

pub_date

2018-11-30 00:00:00

pages

5115

issue

1

issn

2041-1723

pii

10.1038/s41467-018-07484-4

journal_volume

9

pub_type

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