Abstract：
:Highly selective hydrogenative carbon-carbon bond scission of biomass-derived platform oxygenates was achieved with a cerium oxide-supported ruthenium nanoparticle catalyst in water. The present catalyst enabled the selective cleavage of carbon-carbon σ bonds adjacent to carboxyl, ester, and hydroxymethyl groups, opening new eight synthetic routes to valuable chemicals from biomass derivatives. The high selectivity for such carbon-carbon bond scission over carbon-oxygen bonds was attributed to the multiple catalytic roles of the Ru nanoparticles assisted by the in situ formed Ce(OH)3.
journal_name
Sci Repjournal_title
Scientific reportsauthors
Mizugaki T,Togo K,Maeno Z,Mitsudome T,Jitsukawa K,Kaneda Kdoi
10.1038/s41598-017-14373-1subject
Has Abstractpub_date
2017-10-25 00:00:00pages
14007issue
1issn
2045-2322pii
10.1038/s41598-017-14373-1journal_volume
7pub_type
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