Abstract：
:The discovery of graphene kicked off the curtain of atom-type two-dimensional (2D) materials. Layered metal-organic frameworks (MOFs) as parallel molecule-based 2D materials are more designable and more diverse, and magnetism may be induced by their metal ion nodes. However, the multifunctional 2D plane-like MOFs are very difficult to obtain. Here we describe a Chinese pane-like 2D MOF constructed from the Ln3+ cation and the nanoscale luminescent tritopic ligand tris(4'-carboxybiphenyl)-amine, responding to the slow magnetic relaxation and luminescence properties, respectively. Notably, the Dy-Dy distances separated by the tritopic ligand are up to 2 nm. Such a 2D molecular material is expected to have potential applications in optoelectronics and multimodal sensing.
journal_name
Sci Repjournal_title
Scientific reportsauthors
Liu CM,Zhang DQ,Hao X,Zhu DBdoi
10.1038/s41598-017-11006-5subject
Has Abstractpub_date
2017-09-11 00:00:00pages
11156issue
1issn
2045-2322pii
10.1038/s41598-017-11006-5journal_volume
7pub_type
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