Differential electron emission from polycyclic aromatic hydrocarbon molecules under fast ion impact.

Abstract:

:Interaction between polycyclic aromatic hydrocarbon (PAH) molecule and energetic ion is a subject of interest in different areas of modern physics. Here, we present measurements of energy and angular distributions of absolute double differential electron emission cross section for coronene (C24H12) and fluorene (C13H10) molecules under fast bare oxygen ion impact. For coronene, the angular distributions of the low energy electrons are quite different from that of simpler targets like Ne or CH4, which is not the case for fluorene. The behaviour of the higher electron energy distributions for both the targets are similar to that for simple targets. In case of coronene, a clear signature of plasmon resonance is observed in the analysis of forward-backward angular asymmetry of low energy electron emission. For fluorene, such signature is not identified probably due to lower oscillator strength of plasmon compared to the coronene. The theoretical calculation based on the first-order Born approximation with correct boundary conditions (CB1), in general, reproduced the experimental observations qualitatively, for both the molecules, except in the low energy region for coronene, which again indicates the role of collective excitation. Single differential and total cross sections are also deduced. An overall comparative study is presented.

journal_name

Sci Rep

journal_title

Scientific reports

authors

Biswas S,Champion C,Weck PF,Tribedi LC

doi

10.1038/s41598-017-05149-8

subject

Has Abstract

pub_date

2017-07-17 00:00:00

pages

5560

issue

1

issn

2045-2322

pii

10.1038/s41598-017-05149-8

journal_volume

7

pub_type

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