Non-syngas direct steam reforming of methanol to hydrogen and carbon dioxide at low temperature.

Abstract:

:A non-syngas direct steam reforming route is investigated for the conversion of methanol to hydrogen and carbon dioxide over a CuZnGaO(x) catalyst at 150-200 °C. This route is in marked contrast with the conventional complex route involving steam reformation to syngas (CO/H2) at high temperature, followed by water gas shift and CO cleanup stages for hydrogen production. Here we report that high quality hydrogen and carbon dioxide can be produced in a single-step reaction over the catalyst, with no detectable CO (below detection limit of 1 ppm). This can be used to supply proton exchange membrane fuel cells for mobile applications without invoking any CO shift and cleanup stages. The working catalyst contains, on average, 3-4 nm copper particles, alongside extremely small size of copper clusters stabilized on a defective ZnGa2O4 spinel oxide surface, providing hydrogen productivity of 393.6 ml g(-1)-cat h(-1) at 150 °C.

journal_name

Nat Commun

journal_title

Nature communications

authors

Yu KM,Tong W,West A,Cheung K,Li T,Smith G,Guo Y,Tsang SC

doi

10.1038/ncomms2242

subject

Has Abstract

pub_date

2012-01-01 00:00:00

pages

1230

issn

2041-1723

pii

ncomms2242

journal_volume

3

pub_type

杂志文章
  • Fonio millet genome unlocks African orphan crop diversity for agriculture in a changing climate.

    abstract::Sustainable food production in the context of climate change necessitates diversification of agriculture and a more efficient utilization of plant genetic resources. Fonio millet (Digitaria exilis) is an orphan African cereal crop with a great potential for dryland agriculture. Here, we establish high-quality genomic ...

    journal_title:Nature communications

    pub_type: 杂志文章

    doi:10.1038/s41467-020-18329-4

    authors: Abrouk M,Ahmed HI,Cubry P,Šimoníková D,Cauet S,Pailles Y,Bettgenhaeuser J,Gapa L,Scarcelli N,Couderc M,Zekraoui L,Kathiresan N,Čížková J,Hřibová E,Doležel J,Arribat S,Bergès H,Wieringa JJ,Gueye M,Kane NA,Leclerc C

    更新日期:2020-09-08 00:00:00

  • Histamine H3 receptors aggravate cerebral ischaemic injury by histamine-independent mechanisms.

    abstract::The role of the histamine H3 receptor (H3R) in cerebral ischaemia/reperfusion (I/R) injury remains unknown. Here we show that H3R expression is upregulated after I/R in two mouse models. H3R antagonists and H3R knockout attenuate I/R injury, which is reversed by an H3R-selective agonist. Interestingly, H1R and H2R ant...

    journal_title:Nature communications

    pub_type: 杂志文章

    doi:10.1038/ncomms4334

    authors: Yan H,Zhang X,Hu W,Ma J,Hou W,Zhang X,Wang X,Gao J,Shen Y,Lv J,Ohtsu H,Han F,Wang G,Chen Z

    更新日期:2014-02-25 00:00:00

  • Abundant DNA 6mA methylation during early embryogenesis of zebrafish and pig.

    abstract::DNA N6-methyldeoxyadenosine (6mA) is a well-known prokaryotic DNA modification that has been shown to exist and play epigenetic roles in eukaryotic DNA. Here we report that 6mA accumulates up to ∼0.1-0.2% of total deoxyadenosine during early embryogenesis of vertebrates, but diminishes to the background level with the...

    journal_title:Nature communications

    pub_type: 杂志文章

    doi:10.1038/ncomms13052

    authors: Liu J,Zhu Y,Luo GZ,Wang X,Yue Y,Wang X,Zong X,Chen K,Yin H,Fu Y,Han D,Wang Y,Chen D,He C

    更新日期:2016-10-07 00:00:00

  • Variant surface glycoprotein density defines an immune evasion threshold for African trypanosomes undergoing antigenic variation.

    abstract::Trypanosoma brucei is a protozoan parasite that evades its host's adaptive immune response by repeatedly replacing its dense variant surface glycoprotein (VSG) coat from its large genomic VSG repertoire. While the mechanisms regulating VSG gene expression and diversification have been examined extensively, the dynamic...

    journal_title:Nature communications

    pub_type: 杂志文章

    doi:10.1038/s41467-017-00959-w

    authors: Pinger J,Chowdhury S,Papavasiliou FN

    更新日期:2017-10-10 00:00:00

  • Backbone-independent NMR resonance assignments of methyl probes in large proteins.

    abstract::Methyl-specific isotope labeling is a powerful tool to study the structure, dynamics and interactions of large proteins and protein complexes by solution-state NMR. However, widespread applications of this methodology have been limited by challenges in obtaining confident resonance assignments. Here, we present Methyl...

    journal_title:Nature communications

    pub_type: 杂志文章

    doi:10.1038/s41467-021-20984-0

    authors: Nerli S,De Paula VS,McShan AC,Sgourakis NG

    更新日期:2021-01-29 00:00:00

  • Quantum spin Hall phase in 2D trigonal lattice.

    abstract::The quantum spin Hall (QSH) phase is an exotic phenomena in condensed-matter physics. Here we show that a minimal basis of three orbitals (s, px, py) is required to produce a QSH phase via nearest-neighbour hopping in a two-dimensional trigonal lattice. Tight-binding model analyses and calculations show that the QSH p...

    journal_title:Nature communications

    pub_type: 杂志文章

    doi:10.1038/ncomms12746

    authors: Wang ZF,Jin KH,Liu F

    更新日期:2016-09-07 00:00:00

  • Asymmetric construction of tetrahedral chiral zinc with high configurational stability and catalytic activity.

    abstract::Chiral metal complexes show promise as asymmetric catalysts and optical materials. Chiral-at-metal complexes composed of achiral ligands have expanded the versatility and applicability of chiral metal complexes, especially for octahedral and half-sandwich complexes. However, Werner-type tetrahedral complexes with a st...

    journal_title:Nature communications

    pub_type: 杂志文章

    doi:10.1038/s41467-020-20074-7

    authors: Endo K,Liu Y,Ube H,Nagata K,Shionoya M

    更新日期:2020-12-09 00:00:00

  • Energetics of activation of GTP hydrolysis on the ribosome.

    abstract::Several of the steps in protein synthesis on the ribosome utilize hydrolysis of guanosine triphosphate (GTP) as the driving force. This reaction is catalyzed by translation factors that become activated upon binding to the ribosome. The recently determined crystal structure of an elongation factor-Tu ternary complex b...

    journal_title:Nature communications

    pub_type: 杂志文章

    doi:10.1038/ncomms2741

    authors: Wallin G,Kamerlin SC,Aqvist J

    更新日期:2013-01-01 00:00:00

  • Multi-strategic RNA-seq analysis reveals a high-resolution transcriptional landscape in cotton.

    abstract::Cotton is an important natural fiber crop, however, its comprehensive and high-resolution gene map is lacking. Here we integrate four complementary high-throughput techniques, including Pacbio long read Iso-seq, strand-specific RNA-seq, CAGE-seq, and PolyA-seq, to systematically explore the transcription landscape acr...

    journal_title:Nature communications

    pub_type: 杂志文章

    doi:10.1038/s41467-019-12575-x

    authors: Wang K,Wang D,Zheng X,Qin A,Zhou J,Guo B,Chen Y,Wen X,Ye W,Zhou Y,Zhu Y

    更新日期:2019-10-17 00:00:00

  • UMI-linked consensus sequencing enables phylogenetic analysis of directed evolution.

    abstract::The success of protein evolution campaigns is strongly dependent on the sequence context in which mutations are introduced, stemming from pervasive non-additive interactions between a protein's amino acids ('intra-gene epistasis'). Our limited understanding of such epistasis hinders the correct prediction of the funct...

    journal_title:Nature communications

    pub_type: 杂志文章

    doi:10.1038/s41467-020-19687-9

    authors: Zurek PJ,Knyphausen P,Neufeld K,Pushpanath A,Hollfelder F

    更新日期:2020-11-26 00:00:00

  • Hetero-site-specific X-ray pump-probe spectroscopy for femtosecond intramolecular dynamics.

    abstract::New capabilities at X-ray free-electron laser facilities allow the generation of two-colour femtosecond X-ray pulses, opening the possibility of performing ultrafast studies of X-ray-induced phenomena. Particularly, the experimental realization of hetero-site-specific X-ray-pump/X-ray-probe spectroscopy is of special ...

    journal_title:Nature communications

    pub_type: 杂志文章

    doi:10.1038/ncomms11652

    authors: Picón A,Lehmann CS,Bostedt C,Rudenko A,Marinelli A,Osipov T,Rolles D,Berrah N,Bomme C,Bucher M,Doumy G,Erk B,Ferguson KR,Gorkhover T,Ho PJ,Kanter EP,Krässig B,Krzywinski J,Lutman AA,March AM,Moonshiram D,Ray D,

    更新日期:2016-05-23 00:00:00

  • Ultralong UV/mechano-excited room temperature phosphorescence from purely organic cluster excitons.

    abstract::Purely organic room temperature phosphorescence (RTP) has attracted wide attention recently due to its various application potentials. However, ultralong RTP (URTP) with high efficiency is still rarely achieved. Herein, by dissolving 1,8-naphthalic anhydride in certain organic solid hosts, URTP with a lifetime of over...

    journal_title:Nature communications

    pub_type: 杂志文章

    doi:10.1038/s41467-019-13048-x

    authors: Zhang X,Du L,Zhao W,Zhao Z,Xiong Y,He X,Gao PF,Alam P,Wang C,Li Z,Leng J,Liu J,Zhou C,Lam JWY,Phillips DL,Zhang G,Tang BZ

    更新日期:2019-11-14 00:00:00

  • Full-field implementation of a perfect eavesdropper on a quantum cryptography system.

    abstract::Quantum key distribution (QKD) allows two remote parties to grow a shared secret key. Its security is founded on the principles of quantum mechanics, but in reality it significantly relies on the physical implementation. Technological imperfections of QKD systems have been previously explored, but no attack on an esta...

    journal_title:Nature communications

    pub_type: 杂志文章

    doi:10.1038/ncomms1348

    authors: Gerhardt I,Liu Q,Lamas-Linares A,Skaar J,Kurtsiefer C,Makarov V

    更新日期:2011-06-14 00:00:00

  • Efficient sky-blue perovskite light-emitting diodes via photoluminescence enhancement.

    abstract::The efficiencies of green and red perovskite light-emitting diodes (PeLEDs) have been increased close to their theoretical upper limit, while the efficiency of blue PeLEDs is lagging far behind. Here we report enhancing the efficiency of sky-blue PeLEDs by overcoming a major hurdle of low photoluminescence quantum eff...

    journal_title:Nature communications

    pub_type: 杂志文章

    doi:10.1038/s41467-019-13580-w

    authors: Wang Q,Wang X,Yang Z,Zhou N,Deng Y,Zhao J,Xiao X,Rudd P,Moran A,Yan Y,Huang J

    更新日期:2019-12-10 00:00:00

  • Controlling solid-liquid interfacial energy anisotropy through the isotropic liquid.

    abstract::Although the anisotropy of the solid-liquid interfacial free energy for most alloy systems is very small, it plays a crucial role in the growth rate, morphology and crystallographic growth direction of dendrites. Previous work posited a dendrite orientation transition via compositional additions. In this work we exami...

    journal_title:Nature communications

    pub_type: 杂志文章

    doi:10.1038/s41467-020-14530-7

    authors: Wang L,Hoyt JJ,Wang N,Provatas N,Sinclair CW

    更新日期:2020-02-05 00:00:00

  • Author Correction: Molecular basis for the inhibition of the methyl-lysine binding function of 53BP1 by TIRR.

    abstract::The original version of this Article contained an error in the author affiliations. Xiaochun Yu was incorrectly associated with College of Life Sciences, Hebei University, Baoding 071000 Hebei, China.This has now been corrected in both the PDF and HTML versions of the Article. ...

    journal_title:Nature communications

    pub_type: 杂志文章,已发布勘误

    doi:10.1038/s41467-018-08086-w

    authors: Wang J,Yuan Z,Cui Y,Xie R,Yang G,Kassab MA,Wang M,Ma Y,Wu C,Yu X,Liu X

    更新日期:2019-01-08 00:00:00

  • The nasal methylome as a biomarker of asthma and airway inflammation in children.

    abstract::The nasal cellular epigenome may serve as biomarker of airway disease and environmental response. Here we collect nasal swabs from the anterior nares of 547 children (mean-age 12.9 y), and measure DNA methylation (DNAm) with the Infinium MethylationEPIC BeadChip. We perform nasal Epigenome-Wide Association analyses (E...

    journal_title:Nature communications

    pub_type: 杂志文章

    doi:10.1038/s41467-019-11058-3

    authors: Cardenas A,Sordillo JE,Rifas-Shiman SL,Chung W,Liang L,Coull BA,Hivert MF,Lai PS,Forno E,Celedón JC,Litonjua AA,Brennan KJ,DeMeo DL,Baccarelli AA,Oken E,Gold DR

    更新日期:2019-07-12 00:00:00

  • Towards nanoprinting with metals on graphene.

    abstract::Graphene and carbon nanotubes are envisaged as suitable materials for the fabrication of the new generation of nanoelectronics. The controlled patterning of such nanostructures with metal nanoparticles is conditioned by the transfer between a recipient and the surface to pattern. Electromigration under the impact of a...

    journal_title:Nature communications

    pub_type: 杂志文章

    doi:10.1038/ncomms9071

    authors: Melinte G,Moldovan S,Hirlimann C,Liu X,Bégin-Colin S,Bégin D,Banhart F,Pham-Huu C,Ersen O

    更新日期:2015-08-28 00:00:00

  • A complex multi-notch astronomical filter to suppress the bright infrared sky.

    abstract::A long-standing and profound problem in astronomy is the difficulty in obtaining deep near-infrared observations due to the extreme brightness and variability of the night sky at these wavelengths. A solution to this problem is crucial if we are to obtain the deepest possible observations of the early Universe, as red...

    journal_title:Nature communications

    pub_type: 杂志文章

    doi:10.1038/ncomms1584

    authors: Bland-Hawthorn J,Ellis SC,Leon-Saval SG,Haynes R,Roth MM,Löhmannsröben HG,Horton AJ,Cuby JG,Birks TA,Lawrence JS,Gillingham P,Ryder SD,Trinh C

    更新日期:2011-12-06 00:00:00

  • Optical soliton molecular complexes in a passively mode-locked fibre laser.

    abstract::Ultrashort optical pulses propagating in a dissipative nonlinear system can interact and bind stably, forming optical soliton molecules. Soliton molecules in ultrafast lasers are under intense research focus and present striking analogies with their matter molecules counterparts. The recent development of real-time sp...

    journal_title:Nature communications

    pub_type: 杂志文章

    doi:10.1038/s41467-019-08755-4

    authors: Wang ZQ,Nithyanandan K,Coillet A,Tchofo-Dinda P,Grelu P

    更新日期:2019-02-19 00:00:00

  • Silicon carbide-derived carbon nanocomposite as a substitute for mercury in the catalytic hydrochlorination of acetylene.

    abstract::Acetylene hydrochlorination is an important coal-based technology for the industrial production of vinyl chloride, however it is plagued by the toxicity of the mercury chloride catalyst. Therefore extensive efforts have been made to explore alternative catalysts with various metals. Here we report that a nanocomposite...

    journal_title:Nature communications

    pub_type: 杂志文章

    doi:10.1038/ncomms4688

    authors: Li X,Pan X,Yu L,Ren P,Wu X,Sun L,Jiao F,Bao X

    更新日期:2014-04-22 00:00:00

  • Quantitative operando visualization of the energy band depth profile in solar cells.

    abstract::The energy band alignment in solar cell devices is critically important because it largely governs elementary photovoltaic processes, such as the generation, separation, transport, recombination and collection of charge carriers. Despite the expenditure of considerable effort, the measurement of energy band depth prof...

    journal_title:Nature communications

    pub_type: 杂志文章

    doi:10.1038/ncomms8745

    authors: Chen Q,Mao L,Li Y,Kong T,Wu N,Ma C,Bai S,Jin Y,Wu D,Lu W,Wang B,Chen L

    更新日期:2015-07-13 00:00:00

  • Determining the rotation direction in pulsars.

    abstract::Pulsars are rotating neutron stars emitting lighthouse-like beams. Owing to their unique properties, pulsars are a unique astrophysical tool to test general relativity, inform on matter in extreme conditions, and probe galactic magnetic fields. Understanding pulsar physics and emission mechanisms is critical to these ...

    journal_title:Nature communications

    pub_type: 杂志文章

    doi:10.1038/s41467-019-11243-4

    authors: Gueroult R,Shi Y,Rax JM,Fisch NJ

    更新日期:2019-07-19 00:00:00

  • Deciphering key processes controlling rainfall isotopic variability during extreme tropical cyclones.

    abstract::The Mesoamerican and Caribbean (MAC) region is characterized by tropical cyclones (TCs), strong El Niño-Southern Oscillation events, and climate variability that bring unique hazards to socio-ecological systems. Here we report the first characterization of the isotopic evolution of a TC (Hurricane Otto, 2016) in the M...

    journal_title:Nature communications

    pub_type: 杂志文章

    doi:10.1038/s41467-019-12062-3

    authors: Sánchez-Murillo R,Durán-Quesada AM,Esquivel-Hernández G,Rojas-Cantillano D,Birkel C,Welsh K,Sánchez-Llull M,Alonso-Hernández CM,Tetzlaff D,Soulsby C,Boll J,Kurita N,Cobb KM

    更新日期:2019-09-20 00:00:00

  • Discovery and characterization of stable and toxic Tau/phospholipid oligomeric complexes.

    abstract::The microtubule-associated protein Tau plays a central role in the pathogenesis of Alzheimer's disease. Although Tau interaction with membranes is thought to affect some of its physiological functions and its aggregation properties, the sequence determinants and the structural and functional consequences of such inter...

    journal_title:Nature communications

    pub_type: 杂志文章

    doi:10.1038/s41467-017-01575-4

    authors: Ait-Bouziad N,Lv G,Mahul-Mellier AL,Xiao S,Zorludemir G,Eliezer D,Walz T,Lashuel HA

    更新日期:2017-11-22 00:00:00

  • Prosaposin is a regulator of progranulin levels and oligomerization.

    abstract::Progranulin (GRN) loss-of-function mutations leading to progranulin protein (PGRN) haploinsufficiency are prevalent genetic causes of frontotemporal dementia. Reports also indicated PGRN-mediated neuroprotection in models of Alzheimer's and Parkinson's disease; thus, increasing PGRN levels is a promising therapeutic f...

    journal_title:Nature communications

    pub_type: 杂志文章

    doi:10.1038/ncomms11992

    authors: Nicholson AM,Finch NA,Almeida M,Perkerson RB,van Blitterswijk M,Wojtas A,Cenik B,Rotondo S,Inskeep V,Almasy L,Dyer T,Peralta J,Jun G,Wood AR,Frayling TM,Fuchsberger C,Fowler S,Teslovich TM,Manning AK,Kumar S,Curra

    更新日期:2016-06-30 00:00:00

  • Intravenous treatment of choroidal neovascularization by photo-targeted nanoparticles.

    abstract::Choroidal neovascularization (CNV) is the major cause of vision loss in wet age-related macular degeneration (AMD). Current therapies require repeated intravitreal injections, which are painful and can cause infection, bleeding, and retinal detachment. Here we develop nanoparticles (NP-[CPP]) that can be administered ...

    journal_title:Nature communications

    pub_type: 杂志文章

    doi:10.1038/s41467-019-08690-4

    authors: Wang Y,Liu CH,Ji T,Mehta M,Wang W,Marino E,Chen J,Kohane DS

    更新日期:2019-02-18 00:00:00

  • Altered NMDAR signaling underlies autistic-like features in mouse models of CDKL5 deficiency disorder.

    abstract::CDKL5 deficiency disorder (CDD) is characterized by epilepsy, intellectual disability, and autistic features, and CDKL5-deficient mice exhibit a constellation of behavioral phenotypes reminiscent of the human disorder. We previously found that CDKL5 dysfunction in forebrain glutamatergic neurons results in deficits in...

    journal_title:Nature communications

    pub_type: 杂志文章

    doi:10.1038/s41467-019-10689-w

    authors: Tang S,Terzic B,Wang IJ,Sarmiento N,Sizov K,Cui Y,Takano H,Marsh ED,Zhou Z,Coulter DA

    更新日期:2019-06-14 00:00:00

  • Flexible indium-gallium-zinc-oxide Schottky diode operating beyond 2.45 GHz.

    abstract::Mechanically flexible mobile phones have been long anticipated due to the rapid development of thin-film electronics in the last couple of decades. However, to date, no such phone has been developed, largely due to a lack of flexible electronic components that are fast enough for the required wireless communications, ...

    journal_title:Nature communications

    pub_type: 杂志文章

    doi:10.1038/ncomms8561

    authors: Zhang J,Li Y,Zhang B,Wang H,Xin Q,Song A

    更新日期:2015-07-03 00:00:00

  • Piwi reduction in the aged niche eliminates germline stem cells via Toll-GSK3 signaling.

    abstract::Transposons are known to participate in tissue aging, but their effects on aged stem cells remain unclear. Here, we report that in the Drosophila ovarian germline stem cell (GSC) niche, aging-related reductions in expression of Piwi (a transposon silencer) derepress retrotransposons and cause GSC loss. Suppression of ...

    journal_title:Nature communications

    pub_type: 杂志文章

    doi:10.1038/s41467-020-16858-6

    authors: Lin KY,Wang WD,Lin CH,Rastegari E,Su YH,Chang YT,Liao YF,Chang YC,Pi H,Yu BY,Chen SH,Lin CY,Lu MY,Su TY,Tzou FY,Chan CC,Hsu HJ

    更新日期:2020-06-19 00:00:00