Abstract:
:Electrical polarization and depolarization processes of the 45S5 type bioactive glass (BG) was studied by a thermally stimulated depolarization current (TSDC) and an complex impedance measurements. The depolarization processes were found to consist of three processes, which were observed as three peaks, P1, P2 and P3, in the TSDC spectra. P1 and P2, observed at lower than the glass transition temperature, were attributed to the sodium ionic migration from the interstitial positions after polarization procedure coordinated among neighboring silicate and phosphate to stabler positions. This migration process is presumed to relate to a shift in the ionic conductivity elucidated by the ac method. P3 observed at higher temperature for the BG polarized at more than 500 degrees Celsius for long period was ascribed to the ionic migration activated by a local deformation. The depolarization of BG consisted of three processes that depended on the neighboring coordination of traveling sodium ions during polarization.
journal_name
Biomaterialsjournal_title
Biomaterialsauthors
Obata A,Nakamura S,Yamashita Kdoi
10.1016/j.biomaterials.2003.12.028keywords:
subject
Has Abstractpub_date
2004-09-01 00:00:00pages
5163-9issue
21eissn
0142-9612issn
1878-5905pii
S0142961203011773journal_volume
25pub_type
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