Influence of trans-cis isomerisation of coumaric acid substituents on colour variance and stabilisation in anthocyanins.

Abstract:

:The recently isolated pigments from Petunia integrifolia and Triteleia bridgesii present a distinct feature that sheds new light on the understanding of intramolecular copigmentation of anthocyanins. These are among the infrequent anthocyanins that naturally present a coumaric acid substituent in both cis and trans forms. As a consequence, the two isomers demonstrate substantial variations of their thermodynamic and kinetic constants and also colour properties. A possible explanation for these characteristics is presented, making use of molecular modelling and taking into account the three-dimensional structures of the pigments.

journal_name

Phytochemistry

journal_title

Phytochemistry

authors

George F,Figueiredo P,Toki K,Tatsuzawa F,Saito N,Brouillard R

doi

10.1016/s0031-9422(01)00105-4

subject

Has Abstract

pub_date

2001-07-01 00:00:00

pages

791-5

issue

5

eissn

0031-9422

issn

1873-3700

pii

S0031-9422(01)00105-4

journal_volume

57

pub_type

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