Comparisons of photo-fries rearrangements of 4-dodecylphenyl phenylacetate and two structurally related esters in hexane and polyethylene cages. How important are anchoring chains?

Abstract:

:Photo-Fries rearrangements of 4-dodecylphenyl phenylacetate have been investigated in polyethylene films with 0-71% crystallinity and in hexane over a range of temperatures. The results are compared to those reported previously from phenyl phenylacetate and 1-naphthyl tetradecanoate to assess the influence of a long alkyl chain on the in-cage motions of the intermediate singlet radical pairs. It is demonstrated that the reactivity and selectivity of intimate singlet radical pairs can be tuned by judicious placement of long-chain substituents and selection of a specific polyethylene type as the reaction matrix.

journal_name

Photochem Photobiol

authors

Luo C,Passin P,Weiss RG

doi

10.1562/2005-05-26-RA-546

subject

Has Abstract

pub_date

2006-01-01 00:00:00

pages

163-70

issue

1

eissn

0031-8655

issn

1751-1097

pii

2005-05-26-RA-546

journal_volume

82

pub_type

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