Unusual naphthoquinones, catechin and triterpene from Byrsonima microphylla.

Abstract:

:The new triterpene Delta1-lupenone (1), together with lupeol, beta-amyrin and betulin were isolated from the wood of Byrsonima microphylla (Malpighiaceae). The new compounds 3-hydroxy-2-methoxy-8,8,10-trimethyl-8H-antracen-1,4,5-trione (2), 3,7-dihydroxy-2-methoxy-8,8,10-trimethyl-7,8-dihydro-6H-antracen-1,4,5-trione (3), (2S*,10aR*)-2,8-dihydroxy-6-methoxy-1,1,7-trimethyl-2,3,10, 10a-tetrahydro-1H-fenantren-9-one (4) and (2S,3S)-3'-hydroxy-4',5,7-trimethoxy-flavan-3-ol (5) were also isolated through monitored TLC using the antioxidant beta-carotene reagent. The antioxidant potential of the compounds 2-5 was measured and none of them showed activity. The structures of these compounds were elucidated by chemical and spectroscopic analysis based on NMR techniques (1H, 13C NMR, COSY, nOe difference, HMQC and HMBC), UV and MS.

journal_name

Phytochemistry

journal_title

Phytochemistry

authors

Aguiar RM,David JP,David JM

doi

10.1016/j.phytochem.2005.07.011

subject

Has Abstract

pub_date

2005-10-01 00:00:00

pages

2388-92

issue

19

eissn

0031-9422

issn

1873-3700

pii

S0031-9422(05)00351-1

journal_volume

66

pub_type

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