Abstract：
:Harvested forest residues are usually considered a fire hazards and used as "hog-fuel" which results in air pollution. In this study, the biorefinery lignin stream obtained after wet explosion pretreatment and enzymatic hydrolysis of forestry residues of Douglas Fir (FS-10) was characterized and further wet oxidized under alkaline conditions. The studies indicated that at 10% solids, 11.7wt% alkali and 15min residence time, maximum yields were obtained for glucose (12.9wt%), vanillin (0.4wt%) at 230°C; formic acid (11.6wt%) at 250°C; acetic acid (10.7wt%), hydroxybenzaldehyde (0.2wt%), syringaldehyde (0.13wt%) at 280°C; and lactic acid (12.4wt%) at 300°C. FTIR analysis of the solid residue after wet oxidation showed that the aromatic skeletal vibrations relating to lignin compounds increased with temperature indicating that higher severity could result in increased lignin oxidation products. The results obtained, as part of the study, is significant for understanding and optimizing processes for producing high-value bioproducts from forestry residues.
journal_name
Bioresour Technoljournal_title
Bioresource technologyauthors
Srinivas K,de Carvalho Oliveira F,Teller PJ,Gonҫalves AR,Helms GL,Ahring BKdoi
10.1016/j.biortech.2016.09.040subject
Has Abstractpub_date
2016-12-01 00:00:00pages
394-404eissn
0960-8524issn
1873-2976pii
S0960-8524(16)31297-4journal_volume
221pub_type
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