Hydrogen production from oxidative steam reforming of bio-butanol over CoIr-based catalysts: effect of the support.

Abstract:

:This paper studies the influence of the support on the behavior of bimetallic CoIr-based catalysts (6.5 wt.% Co, 0.4 wt.% Ir) for hydrogen production from the oxidative steam reforming of bio-butanol raw mixture (butanol/acetone/ethanol = 6/3/1 mass ratio). Catalytic tests were carried out at 500 °C for 60 h with raw mixture/water/air/Ar = 1/10/7.5/12 molar ratio and GHSV = 7500 h(-1). Over CoIr/18CeZrO(2) and CoIr/ZnO the main process which took place was the oxidative steam reforming of the raw mixture. CoIr/18CeZrO(2) showed the better catalytic performance. Characterization of the used catalysts indicated that both active metal sintering and coke formation was prevented on the CoIr/18CeZrO(2) catalyst.

journal_name

Bioresour Technol

journal_title

Bioresource technology

authors

Cai W,Piscina PR,Gabrowska K,Homs N

doi

10.1016/j.biortech.2012.10.125

subject

Has Abstract

pub_date

2013-01-01 00:00:00

pages

467-71

eissn

0960-8524

issn

1873-2976

pii

S0960-8524(12)01634-3

journal_volume

128

pub_type

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