Abstract:
:This paper studies the influence of the support on the behavior of bimetallic CoIr-based catalysts (6.5 wt.% Co, 0.4 wt.% Ir) for hydrogen production from the oxidative steam reforming of bio-butanol raw mixture (butanol/acetone/ethanol = 6/3/1 mass ratio). Catalytic tests were carried out at 500 °C for 60 h with raw mixture/water/air/Ar = 1/10/7.5/12 molar ratio and GHSV = 7500 h(-1). Over CoIr/18CeZrO(2) and CoIr/ZnO the main process which took place was the oxidative steam reforming of the raw mixture. CoIr/18CeZrO(2) showed the better catalytic performance. Characterization of the used catalysts indicated that both active metal sintering and coke formation was prevented on the CoIr/18CeZrO(2) catalyst.
journal_name
Bioresour Technoljournal_title
Bioresource technologyauthors
Cai W,Piscina PR,Gabrowska K,Homs Ndoi
10.1016/j.biortech.2012.10.125subject
Has Abstractpub_date
2013-01-01 00:00:00pages
467-71eissn
0960-8524issn
1873-2976pii
S0960-8524(12)01634-3journal_volume
128pub_type
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