High-capacity adsorption of dissolved hexavalent chromium using amine-functionalized magnetic corn stalk composites.

Abstract:

:Easily separable amine-functionalized magnetic corn stalk composites (AF-MCS) were employed for effective adsorption and reduction of toxic hexavalent chromium [Cr(VI)] to nontoxic Cr(III). The saturated magnetization of AF-MCS reached 6.2emu/g, and as a result, it could be separated from aqueous solution by a magnetic process for its superparamagnetism. The studies of various factors influencing the sorption behavior indicated that the optimum AF-MCS dosage for Cr(VI) adsorption was 1g/L, and the maximum adsorption capacity was observed at pH 3.0. The chromium adsorption perfectly fitted the Langmuir isotherm model and pseudo second order kinetic model. Furthermore, characterization of AF-MCS was investigated by means of XRD, SEM, TEM, FT-IR, BET, VSM and XPS analysis to discuss the uptake mechanism. Basically, these results demonstrated that AF-MCS prepared in this work has shown its merit in effective removal of Cr(VI) and rapid separation from effluents simultaneously.

journal_name

Bioresour Technol

journal_title

Bioresource technology

authors

Song W,Gao B,Zhang T,Xu X,Huang X,Yu H,Yue Q

doi

10.1016/j.biortech.2015.01.103

subject

Has Abstract

pub_date

2015-08-01 00:00:00

pages

550-7

eissn

0960-8524

issn

1873-2976

pii

S0960-8524(15)00123-6

journal_volume

190

pub_type

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