Abstract:
:Dried biomass of Rhizopus oligosporus produced from food processing wastewater was used as an adsorbent for copper ions in water. The adsorption process was carried out in a batch process and the effects of contact time (1-48 h), initial pH (2.0-6.0), initial metal ion concentration (20-100 mg L(-1)) and temperature (20-38 degrees C) on the adsorption were investigated. Experimental results showed that the maximum adsorption capacity was achieved at pH 5.0 and adsorbed Cu(II) ion concentration was increased with increasing initial metal concentration and contact time. The isothermal data could be described well by the Langmuir equations and monolayer capacity had a mean value of 79.37 mg g(-1). A pseudo-second order reaction model provided the best description of the data with a correlation coefficient 0.99 for different initial metal concentrations. Thermodynamic parameters indicated that biosorption of Cu(II) on R. oligosporus dried biomass was exothermic and spontaneous. To observe the copper pellets on the biosorbent surface after biosorption SEM was used and copper was characterized by EDX. The results of FTIR analyses indicated that amide I and hydroxyl groups of adsorbent played important role in binding Cu(II).
journal_name
Bioresour Technoljournal_title
Bioresource technologyauthors
Ozsoy HD,Kumbur H,Saha B,van Leeuwen JHdoi
10.1016/j.biortech.2007.09.017subject
Has Abstractpub_date
2008-07-01 00:00:00pages
4943-8issue
11eissn
0960-8524issn
1873-2976pii
S0960-8524(07)00759-6journal_volume
99pub_type
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pub_type: 杂志文章,评审
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