Abstract:
:Cephalosporin residue (CR) was used to produce biochar (BC) and activated carbon (AC) at 600°C (BC600 and AC600). To compare the removal behaviors and mechanisms of Cr(VI) by CR and derived chars, batch adsorption tests were performed in Cr(VI) microenvironment like pH, Cr(VI) concentration, adsorbent dosage, combing with the characterization of adsorbents before and after adsorption. Fourier transform-infrared spectroscopy (FT-IR), X-ray diffraction (XRD), scanning electron microscope (SEM), energy dispersive spectroscopy (EDS), and Brunauer-Emmett-Teller (BET) techniques were used. Results showed that the Cr(VI) removals by CR and CR-chars fitted Freundlich and Langmuir models. Based on the Langmuir model, the maximum adsorption capacities of CR, BC600 and AC600 towards Cr(VI) were 107.41, 88.19 and 74.07mgg-1, respectively. The CR rich in dissolved carbon (DOC), -NH2 and -COOH, chiefly acted as chelating and reducing agents, while the AC600 with high surface area mainly supported Cr(VI) adsorption during Cr(VI) removal process.
journal_name
Bioresour Technoljournal_title
Bioresource technologyauthors
Zhang J,Chen S,Zhang H,Wang Xdoi
10.1016/j.biortech.2017.04.081subject
Has Abstractpub_date
2017-08-01 00:00:00pages
484-491eissn
0960-8524issn
1873-2976pii
S0960-8524(17)30588-6journal_volume
238pub_type
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