Abstract:
:Calcium silicate hydrate (C-S-H) is the binder in concrete, the most used synthetic material in the world. The main weakness of concrete is the lack of elasticity and poor flexural strength considerably limiting its potential, making reinforcing steel constructions necessary. Although the properties of C-S-H could be significantly improved in organic hybrids, the full potential of this approach could not be reached because of the random C-S-H nanoplatelet structure. Taking inspiration from a sea urchin spine with highly ordered nanoparticles in the biomineral mesocrystal, we report a bioinspired route toward a C-S-H mesocrystal with highly aligned C-S-H nanoplatelets interspaced with a polymeric binder. A material with a bending strength similar to nacre is obtained, outperforming all C-S-H-based materials known to date. This strategy could greatly benefit future construction processes because fracture toughness and elasticity of brittle cementitious materials can be largely enhanced on the nanoscale.
journal_name
Sci Advjournal_title
Science advancesauthors
Picker A,Nicoleau L,Burghard Z,Bill J,Zlotnikov I,Labbez C,Nonat A,Cölfen Hdoi
10.1126/sciadv.1701216subject
Has Abstractpub_date
2017-11-29 00:00:00pages
e1701216issue
11issn
2375-2548pii
1701216journal_volume
3pub_type
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