Mass spectrometry of hexosamine containing oligosaccharides as permethylated N-trifluoroacetyl derivatives.

Abstract:

:Permethylated N-trifluoroacetyl hexosamine containing oligosaccharide alditols are favorable for analysis by mass spectrometry. Electron impact and fast atom bombardment mass spectra of these derivatives are characterized by strong primary and secondary fragments in which a positive charge is localized on the N-trifluoroacetyl hexosamine residue. From the mass spectra the monosaccharide sequence and the position(s) of substitution of a N-trifluoroacetyl hexosamine can be determined.

journal_name

Adv Exp Med Biol

authors

Nilsson B

doi

10.1007/978-1-4613-1663-3_35

subject

Has Abstract

pub_date

1988-01-01 00:00:00

pages

803-13

eissn

0065-2598

issn

2214-8019

journal_volume

228

pub_type

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