Abstract:
:Novel chiral diisopropyl spiro bis(isoxazoline) ligands, anti-i-Pr-SPRIX and syn-i-Pr-SPRIX, were designed and synthesized. Their catalytic utility, X-ray crystallographic analyses, and complexation studies demonstrated the structural features of tetraisopropyl spiro bis(isoxazoline) ligand, i-Pr-SPRIX, which is a prominent ligand in various enantioselective Pd catalytic processes: All i-Pr groups work in collaboration to create an effective asymmetric environment.
journal_name
Chiralityjournal_title
Chiralityauthors
Takenaka K,Lin X,Takizawa S,Sasai Hdoi
10.1002/chir.22467subject
Has Abstractpub_date
2015-08-01 00:00:00pages
532-7issue
8eissn
0899-0042issn
1520-636Xjournal_volume
27pub_type
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