Abstract:
:The absolute configuration of the acyclic side chain of heptopyranosides and heptofuranosides was determined by exciton coupled CD, employing the strongly fluorescent 2-anthroate chromophore. The usage of this chromophore offers significant improvements over previous chemical and spectroscopic procedures since its intense fluorescence greatly facilitates the isolation and HPLC purification at the nanogram scale. The large amplitudes of the bisignate spectra allow CD manipulations in the 1 x 10(-7) M range.
journal_name
Chiralityjournal_title
Chiralityauthors
Akritopoulou-Zanze I,Nakanishi K,Stepowska H,Grzeszczyk B,Zamojski A,Berova Ndoi
10.1002/(SICI)1520-636X(1997)9:7<699::AID-CHIR11>3subject
Has Abstractpub_date
1997-01-01 00:00:00pages
699-712issue
7eissn
0899-0042issn
1520-636Xpii
10.1002/(SICI)1520-636X(1997)9:7<699::AID-CHIR11>3journal_volume
9pub_type
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