Abstract:
:InCl3, a water-compatible Lewis acid, was used for the conversion of microcrystalline cellulose to produce 5-hydroxymethylfurfural (HMF) in a H2O/THF biphasic system. Addition of NaCl increased the HMF yield significantly but suppressed the levulinic acid (LA) formation. The HMF yield of 39.7% was obtained in 2h at 200°C in the NaCl-H2O/THF catalytic system catalyzed by InCl3. The catalytic system also showed effectiveness to convert other carbohydrates to HMF, including glucose, fructose, sucrose, starch, which demonstrated great potential towards different feedstocks.
journal_name
Bioresour Technoljournal_title
Bioresource technologyauthors
Shen Y,Sun J,Yi Y,Li M,Wang B,Xu F,Sun Rdoi
10.1016/j.biortech.2014.09.077subject
Has Abstractpub_date
2014-11-01 00:00:00pages
457-460eissn
0960-8524issn
1873-2976pii
S0960-8524(14)01336-4journal_volume
172pub_type
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