InCl3-catalyzed conversion of carbohydrates into 5-hydroxymethylfurfural in biphasic system.

Abstract:

:InCl3, a water-compatible Lewis acid, was used for the conversion of microcrystalline cellulose to produce 5-hydroxymethylfurfural (HMF) in a H2O/THF biphasic system. Addition of NaCl increased the HMF yield significantly but suppressed the levulinic acid (LA) formation. The HMF yield of 39.7% was obtained in 2h at 200°C in the NaCl-H2O/THF catalytic system catalyzed by InCl3. The catalytic system also showed effectiveness to convert other carbohydrates to HMF, including glucose, fructose, sucrose, starch, which demonstrated great potential towards different feedstocks.

journal_name

Bioresour Technol

journal_title

Bioresource technology

authors

Shen Y,Sun J,Yi Y,Li M,Wang B,Xu F,Sun R

doi

10.1016/j.biortech.2014.09.077

subject

Has Abstract

pub_date

2014-11-01 00:00:00

pages

457-460

eissn

0960-8524

issn

1873-2976

pii

S0960-8524(14)01336-4

journal_volume

172

pub_type

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