X-ray induced visible luminescence of porphyrins.

Abstract:

:A concept has been presented whereby X-ray irradiation can be used to induce visible luminescence of chromophores such as porphyrins. The essential aspects of the idea have been demonstrated in a supramolecular assembly consisting of a water-dispersed polystyrene latex with an embedded scintillating compound, 2,5-diphenyloxazole, and an externally attached hematoporphyrin. X-ray excitation of the assembly yields an emission spectra typical for hematoporphyrin with fluorescent yields of up to 3% with respect to 2,5-diphenyloxazole emission. Significant quenching in the presence of dioxygen indicates that singlet oxygen is formed at atmospheric conditions.

journal_name

Photochem Photobiol

authors

Kokotov S,Lewis A,Neumann R,Amrusi S

doi

10.1111/j.1751-1097.1994.tb05052.x

subject

Has Abstract

pub_date

1994-03-01 00:00:00

pages

385-7

issue

3

eissn

0031-8655

issn

1751-1097

journal_volume

59

pub_type

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