当前位置： SCI文献检索 > Nature Communications期刊下所有文献 > Unveiling phonons in a molecular qubit with four-dimensional inelastic neutron scattering and density functional theory.

Unveiling phonons in a molecular qubit with four-dimensional inelastic neutron scattering and density functional theory.

Abstract：

:Phonons are the main source of relaxation in molecular nanomagnets, and different mechanisms have been proposed in order to explain the wealth of experimental findings. However, very limited experimental investigations on phonons in these systems have been performed so far, yielding no information about their dispersions. Here we exploit state-of-the-art single-crystal inelastic neutron scattering to directly measure for the first time phonon dispersions in a prototypical molecular qubit. Both acoustic and optical branches are detected in crystals of [VO(acac)[Formula: see text]] along different directions in the reciprocal space. Using energies and polarisation vectors calculated with state-of-the-art Density Functional Theory, we reproduce important qualitative features of [VO(acac)[Formula: see text]] phonon modes, such as the presence of low-lying optical branches. Moreover, we evidence phonon anti-crossings involving acoustic and optical branches, yielding significant transfers of the spin-phonon coupling strength between the different modes.

journal_name

Nat Commun

journal_title

Nature communications

authors

Garlatti E,Tesi L,Lunghi A,Atzori M,Voneshen DJ,Santini P,Sanvito S,Guidi T,Sessoli R,Carretta S

doi

10.1038/s41467-020-15475-7

subject

Has Abstract

pub_date

2020-04-09 00:00:00

pages

1751

issue

1

issn

2041-1723

pii

10.1038/s41467-020-15475-7

journal_volume

11

pub_type

杂志文章

相关文献

Nature Communications文献大全
  • PhyloPhlAn is a new method for improved phylogenetic and taxonomic placement of microbes.

    abstract：:New microbial genomes are constantly being sequenced, and it is crucial to accurately determine their taxonomic identities and evolutionary relationships. Here we report PhyloPhlAn, a new method to assign microbial phylogeny and putative taxonomy using >400 proteins optimized from among 3,737 genomes. This method meas...

    journal_title：Nature communications

    pub_type： 杂志文章

    doi：10.1038/ncomms3304

    authors： Segata N,Börnigen D,Morgan XC,Huttenhower C

    更新日期：2013-01-01 00:00:00

  • Sleep-dependent memory consolidation in infants protects new episodic memories from existing semantic memories.

    abstract：:Any experienced event may be encoded and retained in detail as part of our episodic memory, and may also refer and contribute to our generalized knowledge stored in semantic memory. The beginnings of this declarative memory formation are only poorly understood. Even less is known about the interrelation between episod...

    journal_title：Nature communications

    pub_type： 杂志文章

    doi：10.1038/s41467-020-14850-8

    authors： Friedrich M,Mölle M,Friederici AD,Born J

    更新日期：2020-03-10 00:00:00

  • Multifunctional molecular modulators for perovskite solar cells with over 20% efficiency and high operational stability.

    abstract：:Perovskite solar cells present one of the most prominent photovoltaic technologies, yet their stability, scalability, and engineering at the molecular level remain challenging. We demonstrate a concept of multifunctional molecular modulation of scalable and operationally stable perovskite solar cells that exhibit exce...

    journal_title：Nature communications

    pub_type： 杂志文章

    doi：10.1038/s41467-018-06709-w

    authors： Bi D,Li X,Milić JV,Kubicki DJ,Pellet N,Luo J,LaGrange T,Mettraux P,Emsley L,Zakeeruddin SM,Grätzel M

    更新日期：2018-10-26 00:00:00

  • Supersymmetry in the time domain and its applications in optics.

    abstract：:Supersymmetry is a conjectured symmetry between bosons and fermions aiming at solving fundamental questions in string and quantum field theory. Its subsequent application to quantum mechanics led to a ground-breaking analysis and design machinery, later fruitfully extrapolated to photonics. In all cases, the algebraic...

    journal_title：Nature communications

    pub_type： 杂志文章

    doi：10.1038/s41467-020-14634-0

    authors： García-Meca C,Ortiz AM,Sáez RL

    更新日期：2020-02-10 00:00:00

  • Environmental enrichment ameliorates perinatal brain injury and promotes functional white matter recovery.

    abstract：:Hypoxic damage to the developing brain due to preterm birth causes many anatomical changes, including damage to the periventricular white matter. This results in the loss of glial cells, significant disruptions in myelination, and thereby cognitive and behavioral disabilities seen throughout life. Encouragingly, these...

    journal_title：Nature communications

    pub_type： 杂志文章

    doi：10.1038/s41467-020-14762-7

    authors： Forbes TA,Goldstein EZ,Dupree JL,Jablonska B,Scafidi J,Adams KL,Imamura Y,Hashimoto-Torii K,Gallo V

    更新日期：2020-02-19 00:00:00

  • Complete information acquisition in dynamic force microscopy.

    abstract：:Scanning probe microscopy has emerged as a primary tool for exploring and controlling the nanoworld. A critical part of scanning probe measurements is the information transfer from the tip-surface junction to the measurement system. This process reduces responses at multiple degrees of freedom of the probe to relative...

    journal_title：Nature communications

    pub_type： 杂志文章

    doi：10.1038/ncomms7550

    authors： Belianinov A,Kalinin SV,Jesse S

    更新日期：2015-03-13 00:00:00

  • Inhomogeneity of the ultrafast insulator-to-metal transition dynamics of VO2.

    abstract：:The insulator-metal transition (IMT) of vanadium dioxide (VO2) has remained a long-standing challenge in correlated electron physics since its discovery five decades ago. Most interpretations of experimental observations have implicitly assumed a homogeneous material response. Here we reveal inhomogeneous behaviour of...

    journal_title：Nature communications

    pub_type： 杂志文章

    doi：10.1038/ncomms7849

    authors： O'Callahan BT,Jones AC,Hyung Park J,Cobden DH,Atkin JM,Raschke MB

    更新日期：2015-04-21 00:00:00

  • Rapid single-wavelength lightsheet localization microscopy for clarified tissue.

    abstract：:Optical super-resolution microscopy allows nanoscale imaging of protein molecules in intact biological tissues. However, it is still challenging to perform large volume super-resolution imaging for entire animal organs. Here we develop a single-wavelength Bessel lightsheet method, optimized for refractive-index matchi...

    journal_title：Nature communications

    pub_type： 杂志文章

    doi：10.1038/s41467-019-12715-3

    authors： Chu LA,Lu CH,Yang SM,Liu YT,Feng KL,Tsai YC,Chang WK,Wang WC,Chang SW,Chen P,Lee TK,Hwu YK,Chiang AS,Chen BC

    更新日期：2019-10-18 00:00:00

  • Optoelectronic crystal of artificial atoms in strain-textured molybdenum disulphide.

    abstract：:The isolation of the two-dimensional semiconductor molybdenum disulphide introduced a new optically active material possessing a band gap that can be facilely tuned via elastic strain. As an atomically thin membrane with exceptional strength, monolayer molybdenum disulphide subjected to biaxial strain can embed wide b...

    journal_title：Nature communications

    pub_type： 杂志文章

    doi：10.1038/ncomms8381

    authors： Li H,Contryman AW,Qian X,Ardakani SM,Gong Y,Wang X,Weisse JM,Lee CH,Zhao J,Ajayan PM,Li J,Manoharan HC,Zheng X

    更新日期：2015-06-19 00:00:00

  • Construction and integration of three de novo Japanese human genome assemblies toward a population-specific reference.

    abstract：:The complete human genome sequence is used as a reference for next-generation sequencing analyses. However, some ethnic ancestries are under-represented in the reference genome (e.g., GRCh37) due to its bias toward European and African ancestries. Here, we perform de novo assembly of three Japanese male genomes using ...

    journal_title：Nature communications

    pub_type： 杂志文章

    doi：10.1038/s41467-020-20146-8

    authors： Takayama J,Tadaka S,Yano K,Katsuoka F,Gocho C,Funayama T,Makino S,Okamura Y,Kikuchi A,Sugimoto S,Kawashima J,Otsuki A,Sakurai-Yageta M,Yasuda J,Kure S,Kinoshita K,Yamamoto M,Tamiya G

    更新日期：2021-01-11 00:00:00

  • Structural insight into SUMO chain recognition and manipulation by the ubiquitin ligase RNF4.

    abstract：:The small ubiquitin-like modifier (SUMO) can form polymeric chains that are important signals in cellular processes such as meiosis, genome maintenance and stress response. The SUMO-targeted ubiquitin ligase RNF4 engages with SUMO chains on linked substrates and catalyses their ubiquitination, which targets substrates...

    journal_title：Nature communications

    pub_type： 杂志文章

    doi：10.1038/ncomms5217

    authors： Xu Y,Plechanovová A,Simpson P,Marchant J,Leidecker O,Kraatz S,Hay RT,Matthews SJ

    更新日期：2014-06-27 00:00:00

  • Autophagy is a gatekeeper of hepatic differentiation and carcinogenesis by controlling the degradation of Yap.

    abstract：:Activation of the Hippo pathway effector Yap underlies many liver cancers, however no germline or somatic mutations have been identified. Autophagy maintains essential metabolic functions of the liver, and autophagy-deficient murine models develop benign adenomas and hepatomegaly, which have been attributed to activat...

    journal_title：Nature communications

    pub_type： 杂志文章

    doi：10.1038/s41467-018-07338-z

    authors： Lee YA,Noon LA,Akat KM,Ybanez MD,Lee TF,Berres ML,Fujiwara N,Goossens N,Chou HI,Parvin-Nejad FP,Khambu B,Kramer EGM,Gordon R,Pfleger C,Germain D,John GR,Campbell KN,Yue Z,Yin XM,Cuervo AM,Czaja MJ,Fiel MI,Hosh

    更新日期：2018-11-23 00:00:00

  • ABL1 regulates spindle orientation in adherent cells and mammalian skin.

    abstract：:Despite the growing evidence for the regulated spindle orientation in mammals, a systematic approach for identifying the responsible genes in mammalian cells has not been established. Here we perform a kinase-targeting RNAi screen in HeLa cells and identify ABL1 as a novel regulator of spindle orientation. Knockdown o...

    journal_title：Nature communications

    pub_type： 杂志文章

    doi：10.1038/ncomms1634

    authors： Matsumura S,Hamasaki M,Yamamoto T,Ebisuya M,Sato M,Nishida E,Toyoshima F

    更新日期：2012-01-17 00:00:00

  • Neurons in the primate dorsal striatum signal the uncertainty of object-reward associations.

    abstract：:To learn, obtain reward and survive, humans and other animals must monitor, approach and act on objects that are associated with variable or unknown rewards. However, the neuronal mechanisms that mediate behaviours aimed at uncertain objects are poorly understood. Here we demonstrate that a set of neurons in an intern...

    journal_title：Nature communications

    pub_type： 杂志文章

    doi：10.1038/ncomms12735

    authors： White JK,Monosov IE

    更新日期：2016-09-14 00:00:00

  • Mechanism of early light signaling by the carboxy-terminal output module of Arabidopsis phytochrome B.

    abstract：:Plant phytochromes are thought to transduce light signals by mediating the degradation of phytochrome-interacting transcription factors (PIFs) through the N-terminal photosensory module, while the C-terminal module, including a histidine kinase-related domain (HKRD), does not participate in signaling. Here we show tha...

    journal_title：Nature communications

    pub_type： 杂志文章

    doi：10.1038/s41467-017-02062-6

    authors： Qiu Y,Pasoreck EK,Reddy AK,Nagatani A,Ma W,Chory J,Chen M

    更新日期：2017-12-04 00:00:00

  • TALEN outperforms Cas9 in editing heterochromatin target sites.

    abstract：:Genome editing critically relies on selective recognition of target sites. However, despite recent progress, the underlying search mechanism of genome-editing proteins is not fully understood in the context of cellular chromatin environments. Here, we use single-molecule imaging in live cells to directly study the beh...

    journal_title：Nature communications

    pub_type： 杂志文章

    doi：10.1038/s41467-020-20672-5

    authors： Jain S,Shukla S,Yang C,Zhang M,Fatma Z,Lingamaneni M,Abesteh S,Lane ST,Xiong X,Wang Y,Schroeder CM,Selvin PR,Zhao H

    更新日期：2021-01-27 00:00:00

  • Age and pattern of the southern high-latitude continental end-Permian extinction constrained by multiproxy analysis.

    abstract：:Past studies of the end-Permian extinction (EPE), the largest biotic crisis of the Phanerozoic, have not resolved the timing of events in southern high-latitudes. Here we use palynology coupled with high-precision CA-ID-TIMS dating of euhedral zircons from continental sequences of the Sydney Basin, Australia, to show ...

    journal_title：Nature communications

    pub_type： 杂志文章

    doi：10.1038/s41467-018-07934-z

    authors： Fielding CR,Frank TD,McLoughlin S,Vajda V,Mays C,Tevyaw AP,Winguth A,Winguth C,Nicoll RS,Bocking M,Crowley JL

    更新日期：2019-01-23 00:00:00

  • Integrative functional genomics decodes herpes simplex virus 1.

    abstract：:The predicted 80 open reading frames (ORFs) of herpes simplex virus 1 (HSV-1) have been intensively studied for decades. Here, we unravel the complete viral transcriptome and translatome during lytic infection with base-pair resolution by computational integration of multi-omics data. We identify a total of 201 transc...

    journal_title：Nature communications

    pub_type： 杂志文章

    doi：10.1038/s41467-020-15992-5

    authors： Whisnant AW,Jürges CS,Hennig T,Wyler E,Prusty B,Rutkowski AJ,L'hernault A,Djakovic L,Göbel M,Döring K,Menegatti J,Antrobus R,Matheson NJ,Künzig FWH,Mastrobuoni G,Bielow C,Kempa S,Liang C,Dandekar T,Zimmer R,Landth

    更新日期：2020-04-27 00:00:00

  • Different developmental histories of beta-cells generate functional and proliferative heterogeneity during islet growth.

    abstract：:The proliferative and functional heterogeneity among seemingly uniform cells is a universal phenomenon. Identifying the underlying factors requires single-cell analysis of function and proliferation. Here we show that the pancreatic beta-cells in zebrafish exhibit different growth-promoting and functional properties, ...

    journal_title：Nature communications

    pub_type： 杂志文章

    doi：10.1038/s41467-017-00461-3

    authors： Singh SP,Janjuha S,Hartmann T,Kayisoglu Ö,Konantz J,Birke S,Murawala P,Alfar EA,Murata K,Eugster A,Tsuji N,Morrissey ER,Brand M,Ninov N

    更新日期：2017-09-22 00:00:00

  • Stabilizing hidden room-temperature ferroelectricity via a metastable atomic distortion pattern.

    abstract：:Nonequilibrium atomic structures can host exotic and technologically relevant properties in otherwise conventional materials. Oxygen octahedral rotation forms a fundamental atomic distortion in perovskite oxides, but only a few patterns are predominantly present at equilibrium. This has restricted the range of possibl...

    journal_title：Nature communications

    pub_type： 杂志文章

    doi：10.1038/s41467-020-18741-w

    authors： Kim JR,Jang J,Go KJ,Park SY,Roh CJ,Bonini J,Kim J,Lee HG,Rabe KM,Lee JS,Choi SY,Noh TW,Lee D

    更新日期：2020-10-02 00:00:00

  • Mapping of H3N2 influenza antigenic evolution in China reveals a strategy for vaccine strain recommendation.

    abstract：:One of the primary efforts in influenza vaccine strain recommendation is to monitor through gene sequencing the viral surface protein haemagglutinin (HA) variants that lead to viral antigenic changes. Here we have developed a computational method, denoted as PREDAC, to predict antigenic clusters of influenza A (H3N2) ...

    journal_title：Nature communications

    pub_type： 杂志文章

    doi：10.1038/ncomms1710

    authors： Du X,Dong L,Lan Y,Peng Y,Wu A,Zhang Y,Huang W,Wang D,Wang M,Guo Y,Shu Y,Jiang T

    更新日期：2012-02-28 00:00:00

  • The footprint of column collapse regimes on pyroclastic flow temperatures and plume heights.

    abstract：:The gravitational collapse of eruption columns generates ground-hugging pyroclastic density currents (PDCs) with highly variable temperatures, high enough to be a threat for communities surrounding volcanoes. The reasons for such great temperature variability are debated in terms of eruptive versus transport and empla...

    journal_title：Nature communications

    pub_type： 杂志文章

    doi：10.1038/s41467-019-10337-3

    authors： Trolese M,Cerminara M,Esposti Ongaro T,Giordano G

    更新日期：2019-06-06 00:00:00

  • Phosphorylation of ULK1 affects autophagosome fusion and links chaperone-mediated autophagy to macroautophagy.

    abstract：:The Unc-51 like autophagy activating kinase 1 (ULK1) complex plays a central role in the initiation stage of autophagy. However, the function of ULK1 in the late stage of autophagy is unknown. Here, we report that ULK1, a central kinase of the ULK1 complex involved in autophagy initiation, promotes autophagosome-lysos...

    journal_title：Nature communications

    pub_type： 杂志文章

    doi：10.1038/s41467-018-05449-1

    authors： Wang C,Wang H,Zhang D,Luo W,Liu R,Xu D,Diao L,Liao L,Liu Z

    更新日期：2018-08-28 00:00:00

  • Harnessing the landscape of microbial culture media to predict new organism-media pairings.

    abstract：:Culturing microorganisms is a critical step in understanding and utilizing microbial life. Here we map the landscape of existing culture media by extracting natural-language media recipes into a Known Media Database (KOMODO), which includes >18,000 strain-media combinations, >3300 media variants and compound concentra...

    journal_title：Nature communications

    pub_type： 杂志文章

    doi：10.1038/ncomms9493

    authors： Oberhardt MA,Zarecki R,Gronow S,Lang E,Klenk HP,Gophna U,Ruppin E

    更新日期：2015-10-13 00:00:00

  • A mechanistic theory for aquatic food chain length.

    abstract：:Multiple hypotheses propose an ostensibly disparate array of drivers of food chain length (FCL), with contradictory support from natural settings. Here we posit that the magnitude of vertical energy flux in food webs underlies several drivers of FCL. We show that rising energy flux fuels top-heavy biomass pyramids, pr...

    journal_title：Nature communications

    pub_type： 杂志文章

    doi：10.1038/s41467-017-02157-0

    authors： Ward CL,McCann KS

    更新日期：2017-12-11 00:00:00

  • The iBeetle large-scale RNAi screen reveals gene functions for insect development and physiology.

    abstract：:Genetic screens are powerful tools to identify the genes required for a given biological process. However, for technical reasons, comprehensive screens have been restricted to very few model organisms. Therefore, although deep sequencing is revealing the genes of ever more insect species, the functional studies predom...

    journal_title：Nature communications

    pub_type： 杂志文章

    doi：10.1038/ncomms8822

    authors： Schmitt-Engel C,Schultheis D,Schwirz J,Ströhlein N,Troelenberg N,Majumdar U,Dao VA,Grossmann D,Richter T,Tech M,Dönitz J,Gerischer L,Theis M,Schild I,Trauner J,Koniszewski ND,Küster E,Kittelmann S,Hu Y,Lehmann S,S

    更新日期：2015-07-28 00:00:00

  • Thermotropic phase boundaries in classic ferroelectrics.

    abstract：:High-performance piezoelectrics are lead-based solid solutions that exhibit a so-called morphotropic phase boundary, which separates two competing phases as a function of chemical composition; as a consequence, an intermediate low-symmetry phase with a strong piezoelectric effect arises. In search for environmentally ...

    journal_title：Nature communications

    pub_type： 杂志文章

    doi：10.1038/ncomms4172

    authors： Lummen TT,Gu Y,Wang J,Lei S,Xue F,Kumar A,Barnes AT,Barnes E,Denev S,Belianinov A,Holt M,Morozovska AN,Kalinin SV,Chen LQ,Gopalan V

    更新日期：2014-01-01 00:00:00

  • VCP recruitment to mitochondria causes mitophagy impairment and neurodegeneration in models of Huntington's disease.

    abstract：:Mutant Huntingtin (mtHtt) causes neurodegeneration in Huntington's disease (HD) by evoking defects in the mitochondria, but the underlying mechanisms remains elusive. Our proteomic analysis identifies valosin-containing protein (VCP) as an mtHtt-binding protein on the mitochondria. Here we show that VCP is selectively...

    journal_title：Nature communications

    pub_type： 杂志文章

    doi：10.1038/ncomms12646

    authors： Guo X,Sun X,Hu D,Wang YJ,Fujioka H,Vyas R,Chakrapani S,Joshi AU,Luo Y,Mochly-Rosen D,Qi X

    更新日期：2016-08-26 00:00:00

  • Gating mechanism of elongating β-ketoacyl-ACP synthases.

    abstract：:Carbon-carbon bond forming reactions are essential transformations in natural product biosynthesis. During de novo fatty acid and polyketide biosynthesis, β-ketoacyl-acyl carrier protein (ACP) synthases (KS), catalyze this process via a decarboxylative Claisen-like condensation reaction. KSs must recognize multiple ch...

    journal_title：Nature communications

    pub_type： 杂志文章

    doi：10.1038/s41467-020-15455-x

    authors： Mindrebo JT,Patel A,Kim WE,Davis TD,Chen A,Bartholow TG,La Clair JJ,McCammon JA,Noel JP,Burkart MD

    更新日期：2020-04-07 00:00:00

  • MRN complex-dependent recruitment of ubiquitylated BLM helicase to DSBs negatively regulates DNA repair pathways.

    abstract：:Mutations in BLM in Bloom Syndrome patients predispose them to multiple types of cancers. Here we report that BLM is recruited in a biphasic manner to annotated DSBs. BLM recruitment is dependent on the presence of NBS1, MRE11 and ATM. While ATM activity is essential for BLM recruitment in early phase, it is dispensab...

    journal_title：Nature communications

    pub_type： 杂志文章

    doi：10.1038/s41467-018-03393-8

    authors： Tripathi V,Agarwal H,Priya S,Batra H,Modi P,Pandey M,Saha D,Raghavan SC,Sengupta S

    更新日期：2018-03-09 00:00:00