当前位置： SCI文献检索 > Nature Communications期刊下所有文献 > Coulombic self-ordering upon charging a large-capacity layered cathode material for rechargeable batteries.

Coulombic self-ordering upon charging a large-capacity layered cathode material for rechargeable batteries.

Abstract：

:Lithium- and sodium-rich layered transition-metal oxides have recently been attracting significant interest because of their large capacity achieved by additional oxygen-redox reactions. However, layered transition-metal oxides exhibit structural degradation such as cation migration, layer exfoliation or cracks upon deep charge, which is a major obstacle to achieve higher energy-density batteries. Here we demonstrate a self-repairing phenomenon of stacking faults upon desodiation from an oxygen-redox layered oxide Na2RuO3, realizing much better reversibility of the electrode reaction. The phase transformations upon charging A2MO3 (A: alkali metal) can be dominated by three-dimensional Coulombic attractive interactions driven by the existence of ordered alkali-metal vacancies, leading to counterintuitive self-repairing of stacking faults and progressive ordering upon charging. The cooperatively ordered vacancy in lithium-/sodium-rich layered transition-metal oxides is shown to play an essential role, not only in generating the electro-active nonbonding 2p orbital of neighbouring oxygen but also in stabilizing the phase transformation for highly reversible oxygen-redox reactions.

journal_name

Nat Commun

journal_title

Nature communications

authors

Mortemard de Boisse B,Reynaud M,Ma J,Kikkawa J,Nishimura SI,Casas-Cabanas M,Delmas C,Okubo M,Yamada A

doi

10.1038/s41467-019-09409-1

subject

Has Abstract

pub_date

2019-05-16 00:00:00

pages

2185

issue

1

issn

2041-1723

pii

10.1038/s41467-019-09409-1

journal_volume

10

pub_type

杂志文章

相关文献

Nature Communications文献大全
  • Quadruple bonding between iron and boron in the BFe(CO)3- complex.

    abstract：:While main group elements have four valence orbitals accessible for bonding, quadruple bonding to main group elements is extremely rare. Here we report that main group element boron is able to form quadruple bonding interactions with iron in the BFe(CO)3- anion complex, which has been revealed by quantum chemical inve...

    journal_title：Nature communications

    pub_type： 杂志文章

    doi：10.1038/s41467-019-12767-5

    authors： Chi C,Wang JQ,Hu HS,Zhang YY,Li WL,Meng L,Luo M,Zhou M,Li J

    更新日期：2019-10-17 00:00:00

  • Synergistic effect of quinary molten salts and ruthenium catalyst for high-power-density lithium-carbon dioxide cell.

    abstract：:With a recent increase in interest in metal-gas batteries, the lithium-carbon dioxide cell has attracted considerable attention because of its extraordinary carbon dioxide-capture ability during the discharge process and its potential application as a power source for Mars exploration. However, owing to the stable lit...

    journal_title：Nature communications

    pub_type： 杂志文章

    doi：10.1038/s41467-019-14121-1

    authors： Baek K,Jeon WC,Woo S,Kim JC,Lee JG,An K,Kwak SK,Kang SJ

    更新日期：2020-01-23 00:00:00

  • Identification and characterization of a direct activator of a gene transfer agent.

    abstract：:Gene transfer agents (GTAs) are thought to be ancient bacteriophages that have been co-opted into serving their host and can now transfer any gene between bacteria. Production of GTAs is controlled by several global regulators through unclear mechanisms. In Rhodobacter capsulatus, gene rcc01865 encodes a putative regu...

    journal_title：Nature communications

    pub_type： 杂志文章

    doi：10.1038/s41467-019-08526-1

    authors： Fogg PCM

    更新日期：2019-02-05 00:00:00

  • Methane seep carbonates yield clumped isotope signatures out of equilibrium with formation temperatures.

    abstract：:Methane cold seep systems typically exhibit extensive buildups of authigenic carbonate minerals, resulting from local increases in alkalinity driven by methane oxidation. Here, we demonstrate that modern seep authigenic carbonates exhibit anomalously low clumped isotope values (Δ47), as much as ∼0.2‰ lower than expect...

    journal_title：Nature communications

    pub_type： 杂志文章

    doi：10.1038/ncomms12274

    authors： Loyd SJ,Sample J,Tripati RE,Defliese WF,Brooks K,Hovland M,Torres M,Marlow J,Hancock LG,Martin R,Lyons T,Tripati AE

    更新日期：2016-07-22 00:00:00

  • A potent antimalarial benzoxaborole targets a Plasmodium falciparum cleavage and polyadenylation specificity factor homologue.

    abstract：:Benzoxaboroles are effective against bacterial, fungal and protozoan pathogens. We report potent activity of the benzoxaborole AN3661 against Plasmodium falciparum laboratory-adapted strains (mean IC50 32 nM), Ugandan field isolates (mean ex vivo IC50 64 nM), and murine P. berghei and P. falciparum infections (day 4 E...

    journal_title：Nature communications

    pub_type： 杂志文章

    doi：10.1038/ncomms14574

    authors： Sonoiki E,Ng CL,Lee MC,Guo D,Zhang YK,Zhou Y,Alley MR,Ahyong V,Sanz LM,Lafuente-Monasterio MJ,Dong C,Schupp PG,Gut J,Legac J,Cooper RA,Gamo FJ,DeRisi J,Freund YR,Fidock DA,Rosenthal PJ

    更新日期：2017-03-06 00:00:00

  • A neural link between generosity and happiness.

    abstract：:Generous behaviour is known to increase happiness, which could thereby motivate generosity. In this study, we use functional magnetic resonance imaging and a public pledge for future generosity to investigate the brain mechanisms that link generous behaviour with increases in happiness. Participants promised to spend ...

    journal_title：Nature communications

    pub_type： 杂志文章

    doi：10.1038/ncomms15964

    authors： Park SQ,Kahnt T,Dogan A,Strang S,Fehr E,Tobler PN

    更新日期：2017-07-11 00:00:00

  • 4D Visualization of replication foci in mammalian cells corresponding to individual replicons.

    abstract：:Since the pioneering proposal of the replicon model of DNA replication 50 years ago, the predicted replicons have not been identified and quantified at the cellular level. Here, we combine conventional and super-resolution microscopy of replication sites in live and fixed cells with computational image analysis. We co...

    journal_title：Nature communications

    pub_type： 杂志文章

    doi：10.1038/ncomms11231

    authors： Chagin VO,Casas-Delucchi CS,Reinhart M,Schermelleh L,Markaki Y,Maiser A,Bolius JJ,Bensimon A,Fillies M,Domaing P,Rozanov YM,Leonhardt H,Cardoso MC

    更新日期：2016-04-07 00:00:00

  • Charge order from orbital-dependent coupling evidenced by NbSe2.

    abstract：:Niobium diselenide has long served as a prototype of two-dimensional charge ordering, believed to arise from an instability of the electronic structure analogous to the one-dimensional Peierls mechanism. Despite this, various anomalous properties have recently been identified experimentally, which cannot be explained ...

    journal_title：Nature communications

    pub_type： 杂志文章

    doi：10.1038/ncomms8034

    authors： Flicker F,van Wezel J

    更新日期：2015-05-07 00:00:00

  • Towards ultrafast dynamics with split-pulse X-ray photon correlation spectroscopy at free electron laser sources.

    abstract：:One of the important challenges in condensed matter science is to understand ultrafast, atomic-scale fluctuations that dictate dynamic processes in equilibrium and non-equilibrium materials. Here, we report an important step towards reaching that goal by using a state-of-the-art perfect crystal based split-and-delay s...

    journal_title：Nature communications

    pub_type： 杂志文章

    doi：10.1038/s41467-018-04178-9

    authors： Roseker W,Hruszkewycz SO,Lehmkühler F,Walther M,Schulte-Schrepping H,Lee S,Osaka T,Strüder L,Hartmann R,Sikorski M,Song S,Robert A,Fuoss PH,Sutton M,Stephenson GB,Grübel G

    更新日期：2018-04-27 00:00:00

  • Truncation and constitutive activation of the androgen receptor by diverse genomic rearrangements in prostate cancer.

    abstract：:Molecularly targeted therapies for advanced prostate cancer include castration modalities that suppress ligand-dependent transcriptional activity of the androgen receptor (AR). However, persistent AR signalling undermines therapeutic efficacy and promotes progression to lethal castration-resistant prostate cancer (CRP...

    journal_title：Nature communications

    pub_type： 杂志文章

    doi：10.1038/ncomms13668

    authors： Henzler C,Li Y,Yang R,McBride T,Ho Y,Sprenger C,Liu G,Coleman I,Lakely B,Li R,Ma S,Landman SR,Kumar V,Hwang TH,Raj GV,Higano CS,Morrissey C,Nelson PS,Plymate SR,Dehm SM

    更新日期：2016-11-29 00:00:00

  • Switching of band inversion and topological surface states by charge density wave.

    abstract：:Topologically nontrivial materials host protected edge states associated with the bulk band inversion through the bulk-edge correspondence. Manipulating such edge states is highly desired for developing new functions and devices practically using their dissipation-less nature and spin-momentum locking. Here we introdu...

    journal_title：Nature communications

    pub_type： 杂志文章

    doi：10.1038/s41467-020-16290-w

    authors： Mitsuishi N,Sugita Y,Bahramy MS,Kamitani M,Sonobe T,Sakano M,Shimojima T,Takahashi H,Sakai H,Horiba K,Kumigashira H,Taguchi K,Miyamoto K,Okuda T,Ishiwata S,Motome Y,Ishizaka K

    更新日期：2020-05-18 00:00:00

  • Geochemistry of silicate-rich rocks can curtail spreading of carbon dioxide in subsurface aquifers.

    abstract：:Pools of carbon dioxide are found in natural geological accumulations and in engineered storage in saline aquifers. It has been thought that once this CO2 dissolves in the formation water, making it denser, convection streams will transport it efficiently to depth, but this may not be so. Here, we assess theoretically...

    journal_title：Nature communications

    pub_type： 杂志文章

    doi：10.1038/ncomms6743

    authors： Cardoso SS,Andres JT

    更新日期：2014-12-11 00:00:00

  • Optical sinc-shaped Nyquist pulses of exceptional quality.

    abstract：:Sinc-shaped Nyquist pulses possess a rectangular spectrum, enabling data to be encoded in a minimum spectral bandwidth and satisfying by essence the Nyquist criterion of zero inter-symbol interference (ISI). This property makes them very attractive for communication systems since data transmission rates can be maximiz...

    journal_title：Nature communications

    pub_type： 杂志文章

    doi：10.1038/ncomms3898

    authors： Soto MA,Alem M,Amin Shoaie M,Vedadi A,Brès CS,Thévenaz L,Schneider T

    更新日期：2013-01-01 00:00:00

  • Epigenetic modulation of inflammation and synaptic plasticity promotes resilience against stress in mice.

    abstract：:Major depressive disorder is associated with abnormalities in the brain and the immune system. Chronic stress in animals showed that epigenetic and inflammatory mechanisms play important roles in mediating resilience and susceptibility to depression. Here, through a high-throughput screening, we identify two phytochem...

    journal_title：Nature communications

    pub_type： 杂志文章

    doi：10.1038/s41467-017-02794-5

    authors： Wang J,Hodes GE,Zhang H,Zhang S,Zhao W,Golden SA,Bi W,Menard C,Kana V,Leboeuf M,Xie M,Bregman D,Pfau ML,Flanigan ME,Esteban-Fernández A,Yemul S,Sharma A,Ho L,Dixon R,Merad M,Han MH,Russo SJ,Pasinetti GM

    更新日期：2018-02-02 00:00:00

  • Quantitative fermentation of unpretreated transgenic poplar by Caldicellulosiruptor bescii.

    abstract：:Microbial fermentation of lignocellulosic biomass to produce industrial chemicals is exacerbated by the recalcitrant network of lignin, cellulose and hemicelluloses comprising the plant secondary cell wall. In this study, we show that transgenic poplar (Populus trichocarpa) lines can be solubilized without any pretrea...

    journal_title：Nature communications

    pub_type： 杂志文章

    doi：10.1038/s41467-019-11376-6

    authors： Straub CT,Khatibi PA,Wang JP,Conway JM,Williams-Rhaesa AM,Peszlen IM,Chiang VL,Adams MWW,Kelly RM

    更新日期：2019-08-07 00:00:00

  • Amplification of heat extremes by plant CO2 physiological forcing.

    abstract：:Plants influence extreme heat events by regulating land-atmosphere water and energy exchanges. The contribution of plants to changes in future heat extremes will depend on the responses of vegetation growth and physiology to the direct and indirect effects of elevated CO2. Here we use a suite of earth system models to...

    journal_title：Nature communications

    pub_type： 杂志文章

    doi：10.1038/s41467-018-03472-w

    authors： Skinner CB,Poulsen CJ,Mankin JS

    更新日期：2018-03-15 00:00:00

  • Molecular structure of promoter-bound yeast TFIID.

    abstract：:Transcription preinitiation complex assembly on the promoters of protein encoding genes is nucleated in vivo by TFIID composed of the TATA-box Binding Protein (TBP) and 13 TBP-associate factors (Tafs) providing regulatory and chromatin binding functions. Here we present the cryo-electron microscopy structure of promot...

    journal_title：Nature communications

    pub_type： 杂志文章

    doi：10.1038/s41467-018-07096-y

    authors： Kolesnikova O,Ben-Shem A,Luo J,Ranish J,Schultz P,Papai G

    更新日期：2018-11-07 00:00:00

  • Bond percolation in coloured and multiplex networks.

    abstract：:Percolation in complex networks is a process that mimics network degradation and a tool that reveals peculiarities of the network structure. During the course of percolation, the emergent properties of networks undergo non-trivial transformations, which include a phase transition in the connectivity, and in some speci...

    journal_title：Nature communications

    pub_type： 杂志文章

    doi：10.1038/s41467-018-08009-9

    authors： Kryven I

    更新日期：2019-01-24 00:00:00

  • A number-based inventory of size-resolved black carbon particle emissions by global civil aviation.

    abstract：:With the rapidly growing global air traffic, the impacts of the black carbon (BC) in the aviation exhaust on climate, environment and public health are likely rising. The particle number and size distribution are crucial metrics for toxicological analysis and aerosol-cloud interactions. Here, a size-resolved BC partic...

    journal_title：Nature communications

    pub_type： 杂志文章

    doi：10.1038/s41467-019-08491-9

    authors： Zhang X,Chen X,Wang J

    更新日期：2019-02-01 00:00:00

  • Genome-wide association study identifies a new susceptibility locus for cleft lip with or without a cleft palate.

    abstract：:Nonsyndromic cleft lip with or without a cleft palate (NSCL/P) is among the most common human congenital birth defects and imposes a substantial physical and financial burden on affected individuals. Here, we conduct a case-control-based GWAS followed by two rounds of replication; we include six independent cohorts fr...

    journal_title：Nature communications

    pub_type： 杂志文章,meta分析

    doi：10.1038/ncomms7414

    authors： Sun Y,Huang Y,Yin A,Pan Y,Wang Y,Wang C,Du Y,Wang M,Lan F,Hu Z,Wang G,Jiang M,Ma J,Zhang X,Ma H,Ma J,Zhang W,Huang Q,Zhou Z,Ma L,Li Y,Jiang H,Xie L,Jiang Y,Shi B,Cheng J,Shen H,Wang L,Yang Y

    更新日期：2015-03-16 00:00:00

  • The structures of two archaeal type IV pili illuminate evolutionary relationships.

    abstract：:We have determined the cryo-electron microscopic (cryo-EM) structures of two archaeal type IV pili (T4P), from Pyrobaculum arsenaticum and Saccharolobus solfataricus, at 3.8 Å and 3.4 Å resolution, respectively. This triples the number of high resolution archaeal T4P structures, and allows us to pinpoint the evolution...

    journal_title：Nature communications

    pub_type： 杂志文章

    doi：10.1038/s41467-020-17268-4

    authors： Wang F,Baquero DP,Su Z,Beltran LC,Prangishvili D,Krupovic M,Egelman EH

    更新日期：2020-07-09 00:00:00

  • Abiotic ligation of DNA oligomers templated by their liquid crystal ordering.

    abstract：:It has been observed that concentrated solutions of short DNA oligomers develop liquid crystal ordering as the result of a hierarchically structured supramolecular self-assembly. In mixtures of oligomers with various degree of complementarity, liquid crystal microdomains are formed via the selective aggregation of tho...

    journal_title：Nature communications

    pub_type： 杂志文章

    doi：10.1038/ncomms7424

    authors： Fraccia TP,Smith GP,Zanchetta G,Paraboschi E,Yi Y,Walba DM,Dieci G,Clark NA,Bellini T

    更新日期：2015-03-10 00:00:00

  • Allosteric cross-talk in chromatin can mediate drug-drug synergy.

    abstract：:Exploitation of drug-drug synergism and allostery could yield superior therapies by capitalizing on the immensely diverse, but highly specific, potential associated with the biological macromolecular landscape. Here we describe a drug-drug synergy mediated by allosteric cross-talk in chromatin, whereby the binding of ...

    journal_title：Nature communications

    pub_type： 杂志文章

    doi：10.1038/ncomms14860

    authors： Adhireksan Z,Palermo G,Riedel T,Ma Z,Muhammad R,Rothlisberger U,Dyson PJ,Davey CA

    更新日期：2017-03-30 00:00:00

  • Elimination of HIV-1-infected cells by broadly neutralizing antibodies.

    abstract：:The Fc region of HIV-1 Env-specific broadly neutralizing antibodies (bNAbs) is required for suppressing viraemia, through mechanisms which remain poorly understood. Here, we identify bNAbs that exert antibody-dependent cellular cytotoxicity (ADCC) in cell culture and kill HIV-1-infected lymphocytes through natural kil...

    journal_title：Nature communications

    pub_type： 杂志文章

    doi：10.1038/ncomms10844

    authors： Bruel T,Guivel-Benhassine F,Amraoui S,Malbec M,Richard L,Bourdic K,Donahue DA,Lorin V,Casartelli N,Noël N,Lambotte O,Mouquet H,Schwartz O

    更新日期：2016-03-03 00:00:00

  • Faster growth of the major prokaryotic versus eukaryotic CO2 fixers in the oligotrophic ocean.

    abstract：:Because maintenance of non-scalable cellular components--membranes and chromosomes--requires an increasing fraction of energy as cell size decreases, miniaturization comes at a considerable energetic cost for a phytoplanktonic cell. Consequently, if eukaryotes can use their superior energetic resources to acquire nutr...

    journal_title：Nature communications

    pub_type： 杂志文章

    doi：10.1038/ncomms4776

    authors： Zubkov MV

    更新日期：2014-04-29 00:00:00

  • The interdependent network of gene regulation and metabolism is robust where it needs to be.

    abstract：:Despite being highly interdependent, the major biochemical networks of the living cell-the networks of interacting genes and of metabolic reactions, respectively-have been approached mostly as separate systems so far. Recently, a framework for interdependent networks has emerged in the context of statistical physics. ...

    journal_title：Nature communications

    pub_type： 杂志文章

    doi：10.1038/s41467-017-00587-4

    authors： Klosik DF,Grimbs A,Bornholdt S,Hütt MT

    更新日期：2017-09-14 00:00:00

  • Confinement-deconfinement transition due to spontaneous symmetry breaking in quantum Hall bilayers.

    abstract：:Band-inverted electron-hole bilayers support quantum spin Hall insulator and exciton condensate phases. Interest in quantum spin Hall effect in these systems has recently put them in the spotlight. We investigate such a bilayer in an external magnetic field. We show that the interlayer correlations lead to formation o...

    journal_title：Nature communications

    pub_type： 杂志文章

    doi：10.1038/ncomms10462

    authors： Pikulin DI,Silvestrov PG,Hyart T

    更新日期：2016-01-25 00:00:00

  • A CD36 ectodomain mediates insect pheromone detection via a putative tunnelling mechanism.

    abstract：:CD36 transmembrane proteins have diverse roles in lipid uptake, cell adhesion and pathogen sensing. Despite numerous in vitro studies, how they act in native cellular contexts is poorly understood. A Drosophila CD36 homologue, sensory neuron membrane protein 1 (SNMP1), was previously shown to facilitate detection of l...

    journal_title：Nature communications

    pub_type： 杂志文章

    doi：10.1038/ncomms11866

    authors： Gomez-Diaz C,Bargeton B,Abuin L,Bukar N,Reina JH,Bartoi T,Graf M,Ong H,Ulbrich MH,Masson JF,Benton R

    更新日期：2016-06-15 00:00:00

  • Targeted and genome-wide sequencing reveal single nucleotide variations impacting specificity of Cas9 in human stem cells.

    abstract：:CRISPR/Cas9 has demonstrated a high-efficiency in site-specific gene targeting. However, potential off-target effects of the Cas9 nuclease represent a major safety concern for any therapeutic application. Here, we knock out the Tafazzin gene by CRISPR/Cas9 in human-induced pluripotent stem cells with 54% efficiency. W...

    journal_title：Nature communications

    pub_type： 杂志文章

    doi：10.1038/ncomms6507

    authors： Yang L,Grishin D,Wang G,Aach J,Zhang CZ,Chari R,Homsy J,Cai X,Zhao Y,Fan JB,Seidman C,Seidman J,Pu W,Church G

    更新日期：2014-11-26 00:00:00

  • Increased prevalence of EPAS1 variant in cattle with high-altitude pulmonary hypertension.

    abstract：:High-altitude pulmonary hypertension (HAPH) has heritable features and is a major cause of death in cattle in the Rocky Mountains, USA. Although multiple genes are likely involved in the genesis of HAPH, to date no major gene variant has been identified. Using whole-exome sequencing, we report the high association of ...

    journal_title：Nature communications

    pub_type： 杂志文章

    doi：10.1038/ncomms7863

    authors： Newman JH,Holt TN,Cogan JD,Womack B,Phillips JA 3rd,Li C,Kendall Z,Stenmark KR,Thomas MG,Brown RD,Riddle SR,West JD,Hamid R

    更新日期：2015-04-15 00:00:00