Differentiating the geographical origin of Ethiopian coffee using XRF- and ICP-based multi-element and stable isotope profiling.

Abstract:

:To test the potential of different analytical tools to determine the geographical origin of Ethiopian coffee, 103 green arabica coffee samples from four coffee regions in Ethiopia were subjected to multi-elements and δ13C, δ15N and δ18O determinations. Multi-elements were determined by using inductively coupled plasma (ICP)- and X-ray fluorescence spectrometry (XRF)-based techniques, and δ13C, δ15N and δ18O were determined by using elemental analyzer-isotope ratio mass spectrometry. Using linear discriminant analysis, XRF-based multi-elements with and without δ13C appeared to be most effective in discriminating the geographical origin of coffee, giving higher classification accuracy (89 and 86%, respectively) than ICP-based multi-elements with and without stable isotopes (80%, each). These results demonstrate the potential of XRF-based multi-element profiling as a relatively fast and low-cost tool to trace the geographical origin of Ethiopian coffee. All together this study offers the proof of concept for a promising method that, upon standardization, could be used for coffee provenance authentication and fraud detection.

journal_name

Food Chem

journal_title

Food chemistry

authors

Worku M,Upadhayay HR,Latruwe K,Taylor A,Blake W,Vanhaecke F,Duchateau L,Boeckx P

doi

10.1016/j.foodchem.2019.03.135

subject

Has Abstract

pub_date

2019-08-30 00:00:00

pages

295-307

eissn

0308-8146

issn

1873-7072

pii

S0308-8146(19)30620-X

journal_volume

290

pub_type

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