Formation and evolution of orientation-specific CO2 chains on nonpolar ZnO(10͞10) surfaces.

Abstract:

:Clarifying the fundamental adsorption and diffusion process of CO2 on single crystal ZnO surfaces is critical in understanding CO2 activation and transformation over ZnO-based catalysts. By using ultrahigh vacuum-Fourier transform infrared spectroscopy (UHV-FTIRS), we observed the fine structures of CO2 vibrational bands on ZnO(100) surfaces, which are the combinations of different vibrational frequencies, originated from CO2 monomer, dimer, trimer and longer polymer chains along [0001] direction according to the density functional theory calculations. Such novel chain adsorption mode results from the relatively large attractive interaction between CO2 and Zn3c atoms in [0001] direction. Further experiments indicate that the short chains at low coverage evolve into long chains through Ostwald ripening by annealing. At higher CO2 coverage (0.7 ML), the as-grown local (2 × 1) phase of chains first evolve into an unstable local (1 × 1) phase below 150 K, and then into a stable well-defined (2 × 1) phase above 150 K.

journal_name

Sci Rep

journal_title

Scientific reports

authors

Cao Y,Yu M,Qi S,Wang T,Huang S,Hu S,Xu M,Yan S

doi

10.1038/srep43442

subject

Has Abstract

pub_date

2017-03-06 00:00:00

pages

43442

issn

2045-2322

pii

srep43442

journal_volume

7

pub_type

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