Determination of phthalate esters in distillates by ultrasound-vortex-assisted dispersive liquid-liquid micro-extraction (USVADLLME) coupled with gas chromatography/mass spectrometry.

Abstract:

:A method for the extraction of phthalate esters (PAEs) by Ultrasound-Vortex-Assisted Dispersive Liquid-Liquid Micro-Extraction (USVADLLME) approach was optimised and applied for the first time to a historical series of brandies. These contaminants are widely spread in the environment as a consequence of about half century of use in different fields of applications. The concern about these substances and the recent legal restrictions of China in distillates import need a quick and sensitive method for their quantification. The proposed method, moreover, is environmentally oriented due to the disposal of micro-quantities of solvent required. In fact, sub-ppm-limits of detection were achieved with a solvent volume as low as 160μL. The analysed samples were within the legal limits, except for some very ancient brandies whose contamination was probably due to a PAEs concentration effect as a consequence of long ageing and for the use of plastic pipelines no more operative.

journal_name

Food Chem

journal_title

Food chemistry

authors

Montevecchi G,Masino F,Zanasi L,Antonelli A

doi

10.1016/j.foodchem.2016.11.019

subject

Has Abstract

pub_date

2017-04-15 00:00:00

pages

1354-1360

eissn

0308-8146

issn

1873-7072

pii

S0308-8146(16)31843-X

journal_volume

221

pub_type

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