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Immobilization of Polyoxometalate in the Metal-Organic Framework rht-MOF-1: Towards a Highly Effective Heterogeneous Catalyst and Dye Scavenger.

Abstract：

:A series of three remarkable complexes [PMo12O40]@[Cu6O(TZI)3(H2O)9]4·OH·31H2O (H3TZI = 5-tetrazolylisophthalic acid; denoted as HLJU-1, HLJU = Heilongjiang University), [SiMo12O40]@[Cu6O(TZI)3(H2O)9]4·32H2O (denoted as HLJU-2), and [PW12O40]@[Cu6O(TZI)3(H2O)6]4·OH·31H2O (denoted as HLJU-3) have been isolated by using simple one-step solvothermal reaction of copper chloride, 5-tetrazolylisophthalic acid (H3TZI), and various Keggin-type polyoxometalates (POMs), respectively. Crystal analysis of HLJU 1-3 reveals that Keggin-type polyoxoanions have been fitted snuggly in the cages of rht-MOF-1 (MOF: metal-organic framework) with large cell volume in a range of 87968-88800 Å(3) and large pore volume of about 68%. HLJU 1-3 exhibit unique catalytic selectivity and reactivity in the oxidation of alkylbenzene with environmental benign oxidant under mild condition in aqueous phase as well as the uptake capacity towards organic pollutants in aqueous solution.

journal_name

Sci Rep

journal_title

Scientific reports

authors

Sun JW,Yan PF,An GH,Sha JQ,Li GM,Yang GY

doi

10.1038/srep25595

subject

Has Abstract

pub_date

2016-05-09 00:00:00

pages

25595

issn

2045-2322

pii

srep25595

journal_volume

6

pub_type

杂志文章

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