Strain-Engineered Graphene Grown on Hexagonal Boron Nitride by Molecular Beam Epitaxy.

Abstract:

:Graphene grown by high temperature molecular beam epitaxy on hexagonal boron nitride (hBN) forms continuous domains with dimensions of order 20 μm, and exhibits moiré patterns with large periodicities, up to ~30 nm, indicating that the layers are highly strained. Topological defects in the moiré patterns are observed and attributed to the relaxation of graphene islands which nucleate at different sites and subsequently coalesce. In addition, cracks are formed leading to strain relaxation, highly anisotropic strain fields, and abrupt boundaries between regions with different moiré periods. These cracks can also be formed by modification of the layers with a local probe resulting in the contraction and physical displacement of graphene layers. The Raman spectra of regions with a large moiré period reveal split and shifted G and 2D peaks confirming the presence of strain. Our work demonstrates a new approach to the growth of epitaxial graphene and a means of generating and modifying strain in graphene.

journal_name

Sci Rep

journal_title

Scientific reports

authors

Summerfield A,Davies A,Cheng TS,Korolkov VV,Cho Y,Mellor CJ,Foxon CT,Khlobystov AN,Watanabe K,Taniguchi T,Eaves L,Novikov SV,Beton PH

doi

10.1038/srep22440

subject

Has Abstract

pub_date

2016-03-01 00:00:00

pages

22440

issn

2045-2322

pii

srep22440

journal_volume

6

pub_type

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