Reversible redox effect on gas permeation of cobalt doped ethoxy polysiloxane (ES40) membranes.

Abstract:

:This work reports the remarkable effect of reversible gas molecular sieving for high temperature gas separation from cobalt doped ethoxy polysiloxane (CoES40) membranes. This effect stemmed from alternating the reducing and oxidising (redox) state of the cobalt particles embedded in the ES40 matrix. The reduced membranes gave the best H2 permeances of 1 × 10(-6) mol m(-2) s(-1) Pa(-1) and H2/N2 permselectivities of 65. The reduction process tailored a molecular gap attributed to changes in the specific volume between the reduced cobalt (Co(OH)2 and CoO) particles in the ES40 structure, thus allowing for the increased diffusion of gases. Upon re-oxidation, the tailored molecular gap became constricted as the particles reversed to Co3O4 resulting a lower gas diffusion, particularly for the larger gases ie. CO2 and N2. The ES40 matrix proved to be structurally rigid enough to withstand the reversible redox effect of cobalt particles across multiple cycles.

journal_name

Sci Rep

journal_title

Scientific reports

authors

Miller CR,Wang DK,Smart S,Diniz da Costa JC

doi

10.1038/srep01648

subject

Has Abstract

pub_date

2013-01-01 00:00:00

pages

1648

issn

2045-2322

pii

srep01648

journal_volume

3

pub_type

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