CPMV-polyelectrolyte-templated gold nanoparticles.

Abstract:

:The use of polyelectrolyte surface-modified Cowpea mosaic virus (CPMV) for the templated synthesis of narrowly dispersed gold nanoparticles is described. The cationic polyelectrolyte, poly(allylamine) hydrochloride (PAH), is electrostatically bound to the external surface of the virus capsid; the polyelectrolyte promotes the adsorption of anionic gold complexes, which are then easily reduced, under mild conditions, to form a metallic gold coating. As expected, the templated gold nanoparticles can be further modified with thiol reagents. In contrast, reaction of polyelectrolyte-modified CPMV (CPMV-PA) with preformed gold nanoparticles results in the self-assembly of large, hexagonally packed, tessellated-spheres.

journal_name

Biomacromolecules

journal_title

Biomacromolecules

authors

Aljabali AA,Lomonossoff GP,Evans DJ

doi

10.1021/bm200499v

subject

Has Abstract

pub_date

2011-07-11 00:00:00

pages

2723-8

issue

7

eissn

1525-7797

issn

1526-4602

journal_volume

12

pub_type

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