Comprehensive multidetector HPSEC study on solution properties of cereal arabinoxylans in aqueous and DMSO solutions.

Abstract:

:The water-soluble arabinoxylans from wheat flour (high, medium, and low viscosity samples) and rye flour (high viscosity sample) were characterized by (1)H NMR spectroscopy and HPSEC with refractive index, light scattering, and viscometric detectors. These cereal arabinoxylans have recently been used as model arabinoxylans in various studies, but their solution properties have not been previously investigated. In this study, two HPSEC eluent systems were used: the water-based system and DMSO-based system. DMSO seemed to be a better solvent than water, especially for arabinoxylans containing a low amount of arabinose substituents. (1)H NMR spectroscopy indicated the structural differences between the analyzed arabinoxylan samples that also affected the hydrodynamic parameters obtained with HPSEC. Influence of arabinose side groups on the solution conformation of arabinoxylans could not be excluded based on our data, despite the role of arabinose substituents being questioned in previous investigations concerning arabinoxylan conformation in solution.

journal_name

Biomacromolecules

journal_title

Biomacromolecules

authors

Pitkänen L,Virkki L,Tenkanen M,Tuomainen P

doi

10.1021/bm9003767

subject

Has Abstract

pub_date

2009-07-13 00:00:00

pages

1962-9

issue

7

eissn

1525-7797

issn

1526-4602

journal_volume

10

pub_type

杂志文章
  • Ultrasensitive Detection of MicroRNA in Tumor Cells and Tissues via Continuous Assembly of DNA Probe.

    abstract::Nucleic acids have been engineered to participate in a wide variety of tasks. Among them, the enzyme-free amplification modes, enzyme-free DNA circuits (EFDCs), and hybridization chain reactions (HCRs) have been widely applied in a series of studies of bioanalysis. We demonstrated here an ultrasensitive hairpin probe-...

    journal_title:Biomacromolecules

    pub_type: 杂志文章

    doi:10.1021/acs.biomac.5b00959

    authors: Liao Y,Fu Y,Wu Y,Huang R,Zhou X,Xing D

    更新日期:2015-11-09 00:00:00

  • Analysis of adsorption function of polyhydroxybutyrate depolymerase from Alcaligenes faecalis T1 by using a quartz crystal microbalance.

    abstract::Enzymatic adsorption and degradation of three types of aliphatic polyester films and two types of polyolefin films by the extracellular PHB depolymerase from Alcaligenes faecalis T1 have been studied by using a quartz crystal microbalance (QCM) technique. Hydrolysis of poly[(R)-3-hydroxybutyrate] was quantitatively fo...

    journal_title:Biomacromolecules

    pub_type: 杂志文章

    doi:10.1021/bm0000844

    authors: Yamashita K,Aoyagi Y,Abe H,Doi Y

    更新日期:2001-04-01 00:00:00

  • Polarity and motility of large polymer-actin complexes.

    abstract::The polarity of polymer-actin complexes obtained by mixing F-actin with synthetic polymers carrying positive charges such as poly(L-lysine), x,y-ionene bromide polymers, and poly(N-[3-(dimethylamino)propyl]acrylamide) (PDMAPAA-Q) have been investigated. Actin complexes formed with poly(L-lysine) and PDMAPAA-Q, which c...

    journal_title:Biomacromolecules

    pub_type: 杂志文章

    doi:10.1021/bm0494038

    authors: Kakugo A,Shikinaka K,Takekawa N,Sugimoto S,Osada Y,Gong JP

    更新日期:2005-03-01 00:00:00

  • Bottom-up synthesis of hyaluronan and its derivatives via enzymatic polymerization: direct incorporation of an amido functional group.

    abstract::This paper reports the synthesis of hyaluronan (HA) and its derivatives via the hyaluronidase-catalyzed polymerization of 2-substituted oxazoline derivative monomers designed as "transition-state analogue substrates". Polymerization of 2-methyl oxazoline monomer from N-acetylhyalobiuronate (GlcAbeta(1-->3)GlcNAc) effe...

    journal_title:Biomacromolecules

    pub_type: 杂志文章

    doi:10.1021/bm049280r

    authors: Ochiai H,Ohmae M,Mori T,Kobayashi S

    更新日期:2005-03-01 00:00:00

  • Thermodynamic and dynamic characteristics of hydroxypropylmethylcellulose adsorbed films at the air-water interface.

    abstract::Surface pressure isotherms and structural and surface dilatational properties of three hydroxypropylmethycelluloses (HPMCs, called E4M, E50LV, and F4M) adsorbed films at the air-water interface were determined. In this work we present evidence that HPMC molecules are able to diffuse and saturate the air-water interfac...

    journal_title:Biomacromolecules

    pub_type: 杂志文章

    doi:10.1021/bm050757o

    authors: Pérez OE,Sánchez CC,Rodríguez Patino JM,Pilosof AM

    更新日期:2006-01-01 00:00:00

  • Polyhydroxybutyrate and its copolymer with polyhydroxyvalerate as biomaterials: influence on progression of stem cell cycle.

    abstract::Poly(3-hydroxybutyrate) (PHB) and poly(3-hydroxybutyrate-co-3-hydroxyvalerate) (PHBV) are biopolyesters reported to provide favorable microenvironments for cell culture and possess potential for tissue engineering applications. Both biopolymers have been investigated for applications in a variety of medical scenarios,...

    journal_title:Biomacromolecules

    pub_type: 杂志文章

    doi:10.1021/bm1007579

    authors: Ahmed T,Marçal H,Lawless M,Wanandy NS,Chiu A,Foster LJ

    更新日期:2010-10-11 00:00:00

  • Collagen fibril structure is affected by collagen concentration and decorin.

    abstract::Collagen fibrils were obtained in vitro by aggregation from acid-soluble type I collagen at different initial concentrations and with the addition of decorin core or intact decorin. All specimens were observed by scanning electron microscopy and atomic force microscopy. In line with the findings of other authors, lack...

    journal_title:Biomacromolecules

    pub_type: 杂志文章

    doi:10.1021/bm070091t

    authors: Raspanti M,Viola M,Sonaggere M,Tira ME,Tenni R

    更新日期:2007-07-01 00:00:00

  • pH- and GSH-Sensitive Hyaluronic Acid-MP Conjugate Micelles for Intracellular Delivery of Doxorubicin to Colon Cancer Cells and Cancer Stem Cells.

    abstract::A dual-sensitive polymeric drug conjugate (HA-SS-MP) was synthesized by conjugating hydrophobic 6-mercaptopurine (MP) to thiolated hyaluronic acid (HA) as the carrier and ligand to deliver doxorubicin (Dox) to parental colon cancer and colon cancer stem cells. Because of the amphiphilic nature of HA-SS-MP, it was self...

    journal_title:Biomacromolecules

    pub_type: 杂志文章

    doi:10.1021/acs.biomac.8b00856

    authors: Debele TA,Yu LY,Yang CS,Shen YA,Lo CL

    更新日期:2018-09-10 00:00:00

  • Analysis using a linear viscoelastic model of the in vitro osmotic kinetics of polydisperse synthetic colloids.

    abstract::This study clarifies the contribution to overall osmotic kinetics of colloid osmotic pressure (Pi) and the interaction of synthetic colloids with the membrane. Solutions (6%) of dextran with weight average molecular weight (MW(w)) 68 800 (DEX 70), dextran with MW(w) 40 000 (DEX 40), hydroxyethyl starch with MW(w) 70 0...

    journal_title:Biomacromolecules

    pub_type: 杂志文章

    doi:10.1021/bm0500143

    authors: Tatara T,Tashiro C

    更新日期:2005-05-01 00:00:00

  • Preparation by grafting onto, characterization, and properties of thermally responsive polymer-decorated cellulose nanocrystals.

    abstract::The grafting of thermosensitive amine-terminated statistical polymers onto the surface of cellulose nanocrystals (CNCs) was achieved by a peptidic coupling reaction, leading to unusual properties like colloidal stability at high ionic strength, surface activity, and thermoreversible aggregation. We have used a large v...

    journal_title:Biomacromolecules

    pub_type: 杂志文章

    doi:10.1021/bm101106c

    authors: Azzam F,Heux L,Putaux JL,Jean B

    更新日期:2010-12-13 00:00:00

  • Suppressing surface reconstruction of superhydrophobic PDMS using a superhydrophilic zwitterionic polymer.

    abstract::Poly(dimethyl siloxane) (PDMS) is extensively used for biomedical applications due to its low cost, ease of fabrication, high durability and flexibility, oxygen permeability, and self-healing properties. PDMS, however, has some significant drawbacks. PDMS endures unacceptably high levels of nonspecific protein fouling...

    journal_title:Biomacromolecules

    pub_type: 杂志文章

    doi:10.1021/bm300399s

    authors: Keefe AJ,Brault ND,Jiang S

    更新日期:2012-05-14 00:00:00

  • Sulfated glycosaminoglycans exploit the conformational plasticity of bone morphogenetic protein-2 (BMP-2) and alter the interaction profile with its receptor.

    abstract::Sulfated glycosaminoglycans (GAGs) can direct cellular processes by interacting with proteins of the extracellular matrix (ECM). In this study we characterize the interaction profiles of chemically sulfated hyaluronan (HA) and chondroitin sulfate (CS) derivatives with bone morphogenetic protein-2 (BMP-2) and investiga...

    journal_title:Biomacromolecules

    pub_type: 杂志文章

    doi:10.1021/bm5006855

    authors: Hintze V,Samsonov SA,Anselmi M,Moeller S,Becher J,Schnabelrauch M,Scharnweber D,Pisabarro MT

    更新日期:2014-08-11 00:00:00

  • In situ controlled release of rhBMP-2 in gelatin-coated 3D porous poly(ε-caprolactone) scaffolds for homogeneous bone tissue formation.

    abstract::In tissue engineering, incorporation of bone morphogenetic protein-2 (BMP-2) into biomaterial scaffolds is an attractive strategy to stimulate bone repair. However, suboptimal release of BMP-2 remains a great concern, which may cause unfavorable bone formation as well as severe inflammation. In this study, genipin-cro...

    journal_title:Biomacromolecules

    pub_type: 杂志文章

    doi:10.1021/bm401309u

    authors: Zhang Q,Tan K,Zhang Y,Ye Z,Tan WS,Lang M

    更新日期:2014-01-13 00:00:00

  • Transepithelial transport of PAMAM dendrimers across isolated rat jejunal mucosae in ussing chambers.

    abstract::Oral delivery remains a challenge for poorly permeable hydrophilic macromolecules. Poly(amido amine) (PAMAM) dendrimers have shown potential for their possible oral delivery. Transepithelial transport of carboxyl-terminated G3.5 and amine-terminated G4 PAMAM dendrimers was assessed using isolated rat jejunal mucosae m...

    journal_title:Biomacromolecules

    pub_type: 杂志文章

    doi:10.1021/bm5004465

    authors: Hubbard D,Ghandehari H,Brayden DJ

    更新日期:2014-08-11 00:00:00

  • Photocurable Hyperbranched Polymer Medical Glue for Water-Resistant Bonding.

    abstract::Medical glue represents a suitable tool to stop wound bleeding, seal wounds, bond tissues, or implant materials. However, the development of a medical glue for durable underwater bonding remains a challenge. Herein, we developed a hydrophobic hyperbranched polymer-based medical glue with water-resistant bonding abilit...

    journal_title:Biomacromolecules

    pub_type: 杂志文章

    doi:10.1021/acs.biomac.0c01302

    authors: Zhang Y,Li X,Zhu Q,Wei W,Liu X

    更新日期:2020-12-14 00:00:00

  • Genetically Encoded Inverse Bolaamphiphiles.

    abstract::Developing new protein-based materials with a programmable assembly is of great scientific interest and technological importance. Inspired by nature's use of post-translational modifications (PTMs) to control the function and location of proteins, we have leveraged lipidation-the PTM of proteins with lipids-to synthes...

    journal_title:Biomacromolecules

    pub_type: 杂志文章

    doi:10.1021/acs.biomac.9b01380

    authors: Hossain MS,Liu X,Maynard TI,Mozhdehi D

    更新日期:2020-02-10 00:00:00

  • Characterization of resilin-based materials for tissue engineering applications.

    abstract::Modular proteins have emerged as powerful tools in tissue engineering because both the mechanical and biochemical properties can be precisely controlled through amino acid sequence. Resilin is an attractive candidate for use in modular proteins because it is well-known for having low stiffness, high fatigue lifetime, ...

    journal_title:Biomacromolecules

    pub_type: 杂志文章

    doi:10.1021/bm301129b

    authors: Renner JN,Cherry KM,Su RS,Liu JC

    更新日期:2012-11-12 00:00:00

  • Shear-induced self-assembly of native silk proteins into fibrils studied by atomic force microscopy.

    abstract::Noncontact mode atomic force microscopy was used to investigate native silk proteins prepared in different ways. Low protein concentrations revealed that single protein molecules exhibit a simple, round shape with apparent diameters of 20-25 nm. Shearing the native protein solutions after extraction from the gland and...

    journal_title:Biomacromolecules

    pub_type: 杂志文章

    doi:10.1021/bm201509b

    authors: Greving I,Cai M,Vollrath F,Schniepp HC

    更新日期:2012-03-12 00:00:00

  • Photoluminescence Control of Cellulose via Surface Functionalization Using Oxidative Polymerization.

    abstract::Control of the photoluminescence properties of cellulose is conducted by introduction of conducting polymers including fluorene (F) and 3-hexylthiophene (3HT) on cellulose surface through FeCl3 oxidative polymerization. The UV-vis absorption peak of cellulose grafted with the 3-hexylthiophene and fluorene copolymer wa...

    journal_title:Biomacromolecules

    pub_type: 杂志文章

    doi:10.1021/acs.biomac.7b01067

    authors: Phung Hai TA,Sugimoto R

    更新日期:2017-12-11 00:00:00

  • Nanoscale Chemical Features of the Natural Fibrous Material Wood.

    abstract::Peak force infrared (PFIR) microscopy is a recently developed approach to acquire multiple chemical and physical material properties simultaneously and with nanometer resolution: topographical features, infrared (IR)-sensitive maps, adhesion, stiffness, and locally resolved IR spectra. This multifunctional mapping is ...

    journal_title:Biomacromolecules

    pub_type: 杂志文章

    doi:10.1021/acs.biomac.0c01028

    authors: Gusenbauer C,Jakob DS,Xu XG,Vezenov DV,Cabane É,Konnerth J

    更新日期:2020-10-12 00:00:00

  • Transparent cellulose films with high gas barrier properties fabricated from aqueous alkali/urea solutions.

    abstract::Transparent and bendable regenerated cellulose films prepared from aqueous alkali (NaOH or LiOH)/urea (AU) solutions exhibit high oxygen barrier properties, which are superior to those of conventional cellophane, poly(vinylidene chloride), and poly(vinyl alcohol). Series of AU cellulose films are prepared from differe...

    journal_title:Biomacromolecules

    pub_type: 杂志文章

    doi:10.1021/bm200766v

    authors: Yang Q,Fukuzumi H,Saito T,Isogai A,Zhang L

    更新日期:2011-07-11 00:00:00

  • Inclusion of 5-[4-(1-dodecanoylpyridinium)]-10,15,20-triphenylporphine in supramolecular aggregates of cationic amphiphilic cyclodextrins: physicochemical characterization of the complexes and strengthening of the antimicrobial photosensitizing activity.

    abstract::Recent findings suggest that visible light-promoted photooxidative processes mediated by sensitizers of appropriate chemical structure could represent a useful tool for properly addressing the problem of the increasing occurrence of infectious diseases caused by multiantibiotic-resistant microbial pathogens. The monoc...

    journal_title:Biomacromolecules

    pub_type: 杂志文章

    doi:10.1021/bm900533r

    authors: Ferro S,Jori G,Sortino S,Stancanelli R,Nikolov P,Tognon G,Ricchelli F,Mazzaglia A

    更新日期:2009-09-14 00:00:00

  • Poly(2-hydroxyethyl methacrylate) for enzyme immobilization: impact on activity and stability of horseradish peroxidase.

    abstract::On the basis of their versatile structure and chemistry as well as tunable mechanical properties, polymer brushes are well-suited as supports for enzyme immobilization. However, a robust surface design is hindered by an inadequate understanding of the impact on activity from the coupling motif and enzyme distribution ...

    journal_title:Biomacromolecules

    pub_type: 杂志文章

    doi:10.1021/bm200173y

    authors: Lane SM,Kuang Z,Yom J,Arifuzzaman S,Genzer J,Farmer B,Naik R,Vaia RA

    更新日期:2011-05-09 00:00:00

  • Formulation of Multifunctional Materials Based on the Reaction of Glyoxalated Lignins and a Nanoclay/Nanosilicate.

    abstract::Two organosolv lignins from different origins, namely, almond shells and maritime pine, were modified by using a nanoclay and nanosilicate. Prior to modification, they were activated via glyoxalation to enhance the reactivity of the lignins and thus ease the introduction of the nanoparticles into their structure. The ...

    journal_title:Biomacromolecules

    pub_type: 杂志文章

    doi:10.1021/acs.biomac.9b00799

    authors: de Hoyos-Martínez PL,Robles E,Khoukh A,Charrier-El Bouhtoury F,Labidi J

    更新日期:2019-09-09 00:00:00

  • Dielectric relaxation spectroscopy of hydrated and dehydrated silk fibroin cast from aqueous solution.

    abstract::The dynamics of silk protein in the presence and absence of water has been investigated by dielectric relaxation spectroscopy (DRS). The silk fibroin film cast from its water solution contains 4-7 wt % bound water molecules, which can be removed by dehydration at 165 °C. Temperature and frequency scans were performed ...

    journal_title:Biomacromolecules

    pub_type: 杂志文章

    doi:10.1021/bm1008316

    authors: Yu L,Hu X,Kaplan D,Cebe P

    更新日期:2010-10-11 00:00:00

  • Relationship between length and degree of polymerization of TEMPO-oxidized cellulose nanofibrils.

    abstract::The influence of 2,2,6,6-tetrametylpiperidine-1-oxyl (TEMPO)-mediated oxidation of wood cellulose and the mechanical disintegration of oxidized cellulose in water on degree of polymerization determined by viscosity measurement (DP(v)) and the apparent length of the TEMPO-oxidized cellulose nanofibrils (TOCNs) was inve...

    journal_title:Biomacromolecules

    pub_type: 杂志文章

    doi:10.1021/bm2017542

    authors: Shinoda R,Saito T,Okita Y,Isogai A

    更新日期:2012-03-12 00:00:00

  • Unraveling the Correlations between Conformation, Lubrication, and Chemical Stability of Bottlebrush Polymers at Interfaces.

    abstract::In the present study, we monitored the conformation and chemical stability of a hydrophilic bottlebrush (BB) polymer in pure water and buffered saline solutions. We correlated these parameters to lubricating and wear protecting properties. Using the surface forces apparatus (SFA), we show that the BB polymer partially...

    journal_title:Biomacromolecules

    pub_type: 杂志文章

    doi:10.1021/acs.biomac.7b01063

    authors: Faivre J,Shrestha BR,Xie G,Delair T,David L,Matyjaszewski K,Banquy X

    更新日期:2017-12-11 00:00:00

  • pH-Sensitive micelles self-assembled from amphiphilic copolymer brush for delivery of poorly water-soluble drugs.

    abstract::A novel pH-sensitive amphiphilic copolymer brush poly(methyl methacrylate-co-methacrylic acid)-b-poly(poly(ethylene glycol) methyl ether monomethacrylate) [P(MMA-co-MAA)-b-PPEGMA] was defined and synthesized by atom transfer radical polymerization (ATRP) technique. The molecular structures and characteristics of this ...

    journal_title:Biomacromolecules

    pub_type: 杂志文章

    doi:10.1021/bm101058w

    authors: Yang YQ,Zheng LS,Guo XD,Qian Y,Zhang LJ

    更新日期:2011-01-10 00:00:00

  • Modular Polymer Antigens To Optimize Immunity.

    abstract::Subunit vaccines can have excellent safety profiles, but their ability to give rise to robust immune responses is often compromised. For glycan-based vaccines, insufficient understanding of B and T cell epitope combinations that yield optimal immune activation hinders optimization. To determine which antigen features ...

    journal_title:Biomacromolecules

    pub_type: 杂志文章

    doi:10.1021/acs.biomac.9b01049

    authors: Bennett NR,Jarvis CM,Alam MM,Zwick DB,Olson JM,Nguyen HV,Johnson JA,Cook ME,Kiessling LL

    更新日期:2019-12-09 00:00:00

  • Influence of Plasticizers on the pH-Dependent Drug Release and Cellular Interactions of Hydroxypropyl Methylcellulose/Zein Vaginal Anti-HIV Films Containing Tenofovir.

    abstract::Vaginal films featuring the pH-dependent release of tenofovir (TFV) were developed for the prevention of sexual transmission of human immunodeficiency syndrome (HIV). Films based on hydroxypropyl methylcellulose and zein were prepared incorporating different plasticizers [oleic acid, lactic acid, glycerol, and polyeth...

    journal_title:Biomacromolecules

    pub_type: 杂志文章

    doi:10.1021/acs.biomac.0c01609

    authors: Notario-Pérez F,Cazorla-Luna R,Martín-Illana A,Galante J,Ruiz-Caro R,Sarmento B,das Neves J,Veiga MD

    更新日期:2021-01-06 00:00:00