Longitudinal unzipping of carbon nanotubes to form graphene nanoribbons.

Abstract:

:Graphene, or single-layered graphite, with its high crystallinity and interesting semimetal electronic properties, has emerged as an exciting two-dimensional material showing great promise for the fabrication of nanoscale devices. Thin, elongated strips of graphene that possess straight edges, termed graphene ribbons, gradually transform from semiconductors to semimetals as their width increases, and represent a particularly versatile variety of graphene. Several lithographic, chemical and synthetic procedures are known to produce microscopic samples of graphene nanoribbons, and one chemical vapour deposition process has successfully produced macroscopic quantities of nanoribbons at 950 degrees C. Here we describe a simple solution-based oxidative process for producing a nearly 100% yield of nanoribbon structures by lengthwise cutting and unravelling of multiwalled carbon nanotube (MWCNT) side walls. Although oxidative shortening of MWCNTs has previously been achieved, lengthwise cutting is hitherto unreported. Ribbon structures with high water solubility are obtained. Subsequent chemical reduction of the nanoribbons from MWCNTs results in restoration of electrical conductivity. These early results affording nanoribbons could eventually lead to applications in fields of electronics and composite materials where bulk quantities of nanoribbons are required.

journal_name

Nature

journal_title

Nature

authors

Kosynkin DV,Higginbotham AL,Sinitskii A,Lomeda JR,Dimiev A,Price BK,Tour JM

doi

10.1038/nature07872

subject

Has Abstract

pub_date

2009-04-16 00:00:00

pages

872-6

issue

7240

eissn

0028-0836

issn

1476-4687

pii

nature07872

journal_volume

458

pub_type

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