Biodegradable thermoplastic composites based on polyvinyl alcohol and algae.

Abstract:

:Algae constitute a largely available, low value material from renewable resources of marine origin to be used for the production of eco-compatible composites. Fibers of the green alga Ulva armoricana from the French coast were positively evaluated for the production of composites with a hydrophilic, eco-compatible polymer, such as poly(vinyl alcohol) (PVA) as continuous matrix by casting of aqueous suspensions and compression molding. PVA, Ulva, and starch were also successfully processed by the melt in the presence of glycerol. Positive results were obtained for film-forming properties and mechanical characteristics also with limited amounts of PVA (40%) attesting for Ulva suitability to be introduced in composites (up to 30%). Degradation in soil of Ulva and an Ulva-based composites outlined a rapid mineralization of Ulva in the selected medium (over 80% in 100 days) while the composite samples underwent a mineralization rate affected by the different component propensity to degradation.

journal_name

Biomacromolecules

journal_title

Biomacromolecules

authors

Chiellini E,Cinelli P,Ilieva VI,Martera M

doi

10.1021/bm701041e

subject

Has Abstract

pub_date

2008-03-01 00:00:00

pages

1007-13

issue

3

eissn

1525-7797

issn

1526-4602

journal_volume

9

pub_type

杂志文章
  • Xanthan and glucomannan mixtures: synergistic interactions and gelation.

    abstract::The synergistic interaction between xanthan and glucomannan in solution and in the gel phase has been studied by circular dichroism spectroscopy and differential scanning calorimetry. The study in solution of the polysaccharidic mixture indicates a preferred stoichiometry of the interaction corresponding to a weight f...

    journal_title:Biomacromolecules

    pub_type: 杂志文章

    doi:10.1021/bm010163v

    authors: Paradossi G,Chiessi E,Barbiroli A,Fessas D

    更新日期:2002-05-01 00:00:00

  • The biosynthesis of starch granules.

    abstract::Although composed simply of glucose polymers, the starch granule is a complex, semicrystalline structure. Much of this complexity arises from the fact that the two primary enzymes of synthesis-starch synthase and starch-branching enzyme-exist as multiple isoforms. Each form has distinct properties and plays a unique r...

    journal_title:Biomacromolecules

    pub_type: 杂志文章,评审

    doi:10.1021/bm000133c

    authors: Smith AM

    更新日期:2001-07-01 00:00:00

  • Modification of Poly(ethylene 2,5-furandicarboxylate) with Biobased 1,5-Pentanediol: Significantly Toughened Copolyesters Retaining High Tensile Strength and O2 Barrier Property.

    abstract::Poly(ethylene 2,5-furandicarboxylate) (PEF) is a biobased polyester characterized by high gas barrier properties as well as high tensile modulus and strength, but poor toughness. Toughening PEF without sacrificing its modulus, strength and gas barrier performance is a great challenge for PEF modification. In this stud...

    journal_title:Biomacromolecules

    pub_type: 杂志文章

    doi:10.1021/acs.biomac.8b01495

    authors: Xie H,Wu L,Li BG,Dubois P

    更新日期:2019-01-14 00:00:00

  • Role of Sacrificial Protein-Metal Bond Exchange in Mussel Byssal Thread Self-Healing.

    abstract::Marine mussels tether to seashore surfaces with byssal threads, proteinaceous fibers that effectively dissipate energy from crashing waves. Protein-metal coordination bonds have been proposed to contribute to the characteristic mechanical and self-healing properties of byssal threads; however, very little is understoo...

    journal_title:Biomacromolecules

    pub_type: 杂志文章

    doi:10.1021/acs.biomac.5b00803

    authors: Schmitt CN,Politi Y,Reinecke A,Harrington MJ

    更新日期:2015-09-14 00:00:00

  • Injectable Polypeptide Hydrogels with Tunable Microenvironment for 3D Spreading and Chondrogenic Differentiation of Bone-Marrow-Derived Mesenchymal Stem Cells.

    abstract::Bone-marrow-derived mesenchymal stem cells (BMSCs) possess vast potential for tissue engineering and regenerative medicine. In this study, an injectable hydrogel comprising poly(l-glutamic acid)-graft-tyramine (PLG-g-TA) with tunable microenvironment was developed via enzyme-catalyzed cross-linking and used as an arti...

    journal_title:Biomacromolecules

    pub_type: 杂志文章

    doi:10.1021/acs.biomac.6b00884

    authors: Ren K,Cui H,Xu Q,He C,Li G,Chen X

    更新日期:2016-12-12 00:00:00

  • A Mössbauer study of the interaction of chitosan and D-glucosamine with iron and its relevance to other metalloenzymes.

    abstract::The interaction of iron with water-soluble polymer chitosan and monomer d-glucosamine is investigated by Mössbauer spectroscopy. The 4.2 K Mössbauer spectrum of Fe-water-soluble chitosan complex indicates the presence of a magnetic pattern and a quadrupole doublet, and analysis of the spectral data leads to the conclu...

    journal_title:Biomacromolecules

    pub_type: 杂志文章

    doi:10.1021/bm020131n

    authors: Bhatia SC,Ravi N

    更新日期:2003-05-01 00:00:00

  • Influence of enzymatic specificity on the behavior of ephemeral gels.

    abstract::Ephemeral gels, called Enzgels, successively undergo sol-gel and then gel-sol transition under the action of two antagonistic enzymes, transglutaminase and protease. Molecular and macroscopic properties of Enzgels are directly dependent on the enzymatic activities and their ratios. This work studies the characteristic...

    journal_title:Biomacromolecules

    pub_type: 杂志文章

    doi:10.1021/bm700601n

    authors: Picard J,Giraudier S,Larreta-Garde V

    更新日期:2008-01-01 00:00:00

  • Engineering interaction between bone marrow derived endothelial cells and electrospun surfaces for artificial vascular graft applications.

    abstract::The aim of this investigation was to understand and engineer the interactions between endothelial cells and the electrospun (ES) polyvinylidene fluoride-co-hexafluoropropylene (PVDF-HFP) nanofiber surfaces and evaluate their potential for endothelialization. Elastomeric PVDF-HFP samples were electrospun to evaluate th...

    journal_title:Biomacromolecules

    pub_type: 杂志文章

    doi:10.1021/bm401825c

    authors: Ahmed F,Dutta NK,Zannettino A,Vandyke K,Choudhury NR

    更新日期:2014-04-14 00:00:00

  • Spectral properties and DNA targeting features of a thiazole orange-peptide bioconjugate.

    abstract::The molecular recognition features of a DNA-sensitive fluorescent bioconjugate capable of targeting a specific DNA sequence with high efficiency are described. The bioconjugate combines a polypeptide from the Tc3 transposase DNA-binding domain with the dsDNA-sensitive fluorophore thiazole orange. Fluorescence spectros...

    journal_title:Biomacromolecules

    pub_type: 杂志文章

    doi:10.1021/bm070334h

    authors: Thompson M

    更新日期:2007-11-01 00:00:00

  • Conformational changes and molecular mobility in plasticized proteins.

    abstract::Most biopolymers exist in a plasticized state, whether it is naturally with water or unnaturally with glycerol or other suitable polyol, to make a flexible material. We have found that the extent to which a biopolymer can be plasticized is dependent on its molecular and higher order structures outside of simply molecu...

    journal_title:Biomacromolecules

    pub_type: 杂志文章

    doi:10.1021/bm800759g

    authors: Athamneh AI,Griffin M,Whaley M,Barone JR

    更新日期:2008-11-01 00:00:00

  • Patterning Three-Dimensional Hydrogel Microenvironments Using Hyperbranched Polyglycerols for Independent Control of Mesh Size and Stiffness.

    abstract::The extracellular matrix is an environment rich with structural, mechanical, and molecular signals that can impact cell biology. Traditional approaches in hydrogel biomaterial design often rely on modifying the concentration of cross-linking groups to adjust mechanical properties. However, this strategy provides limit...

    journal_title:Biomacromolecules

    pub_type: 杂志文章

    doi:10.1021/acs.biomac.7b00118

    authors: Pedron S,Pritchard AM,Vincil GA,Andrade B,Zimmerman SC,Harley BA

    更新日期:2017-04-10 00:00:00

  • pH-responsive polymeric micelle carriers for siRNA drugs.

    abstract::The ability of small interfering RNA (siRNA) to efficiently silence the expression of specific genes provides the basis for exciting new therapies based on RNA interference (RNAi). The efficient intracellular delivery of siRNA from cell uptake through the endosomal trafficking pathways into the cytoplasm remains a sig...

    journal_title:Biomacromolecules

    pub_type: 杂志文章

    doi:10.1021/bm100652w

    authors: Convertine AJ,Diab C,Prieve M,Paschal A,Hoffman AS,Johnson PH,Stayton PS

    更新日期:2010-11-08 00:00:00

  • Fiber Alignment and Liquid Crystal Orientation of Cellulose Nanocrystals in the Electrospun Nanofibrous Mats.

    abstract::Sulfate cellulose nanocrystal (CNC) dispersions always present specific self-assembled cholesteric mesophases which is easily affected by the inherent properties of particle size, surface charge, and repulsion or affinity interaction, and external field force generated from ionic potential of added electrolytes, magne...

    journal_title:Biomacromolecules

    pub_type: 杂志文章

    doi:10.1021/acs.biomac.7b00927

    authors: Song W,Liu D,Prempeh N,Song R

    更新日期:2017-10-09 00:00:00

  • Reinforcement Effects from Nanodiamond in Cellulose Nanofibril Films.

    abstract::Although research on nanopaper structures from cellulose nanofibrils (CNFs) is well established, the mechanical behavior is not well understood, especially not when CNF is combined with hard nanoparticles. Cationic CNF (Q-CNF) was prepared and successfully decorated by anionic nanodiamond (ND) nanoparticles in hydroco...

    journal_title:Biomacromolecules

    pub_type: 杂志文章

    doi:10.1021/acs.biomac.8b00010

    authors: Morimune-Moriya S,Salajkova M,Zhou Q,Nishino T,Berglund LA

    更新日期:2018-07-09 00:00:00

  • Joining Two Natural Motifs: Catechol-Containing Poly(phosphoester)s.

    abstract::Numerous catechol-containing polymers, including biodegradable polymers, are currently heavily discussed for modern biomaterials. However, there is no report combining poly(phosphoester)s (PPEs) with catechols. Adhesive PPEs have been prepared via acyclic diene metathesis polymerization. A novel acetal-protected catec...

    journal_title:Biomacromolecules

    pub_type: 杂志文章

    doi:10.1021/acs.biomac.6b01613

    authors: Becker G,Ackermann LM,Schechtel E,Klapper M,Tremel W,Wurm FR

    更新日期:2017-03-13 00:00:00

  • Synthesis and biological evaluation of a polysialic acid-based hydrogel as enzymatically degradable scaffold material for tissue engineering.

    abstract::Restorative medicine has a constant need for improved scaffold materials. Degradable biopolymers often suffer from uncontrolled chemical or enzymatic hydrolysis by the host. The need for a second surgery on the other hand is a major drawback for nondegradable scaffold materials. In this paper we report the design and ...

    journal_title:Biomacromolecules

    pub_type: 杂志文章

    doi:10.1021/bm800327s

    authors: Berski S,van Bergeijk J,Schwarzer D,Stark Y,Kasper C,Scheper T,Grothe C,Gerardy-Schahn R,Kirschning A,Dräger G

    更新日期:2008-09-01 00:00:00

  • N-terminal nonrepetitive domain common to dragline, flagelliform, and cylindriform spider silk proteins.

    abstract::Spider silk has been extensively studied for its outstanding mechanical properties. Partial intermediate and C-terminal sequences of different spider silk proteins have been determined, and during the past decade also N-terminal domains have been characterized. However, only some of these N-terminal domains have been ...

    journal_title:Biomacromolecules

    pub_type: 杂志文章

    doi:10.1021/bm060693x

    authors: Rising A,Hjälm G,Engström W,Johansson J

    更新日期:2006-11-01 00:00:00

  • Cross-Linking Chemistry of Tyramine-Modified Hyaluronan Hydrogels Alters Mesenchymal Stem Cell Early Attachment and Behavior.

    abstract::Given the significance of hydrogels as cell-instructive materials, it is important to understand how differences in their chemical and physical properties are able to direct cell fate. For example, it remains unclear how different hydrogel cross-linking chemistries and gelation mechanisms influence cell behavior. Here...

    journal_title:Biomacromolecules

    pub_type: 杂志文章

    doi:10.1021/acs.biomac.6b01740

    authors: Loebel C,Szczesny SE,Cosgrove BD,Alini M,Zenobi-Wong M,Mauck RL,Eglin D

    更新日期:2017-03-13 00:00:00

  • CXCR4-Targeted and Redox Responsive Dextrin Nanogel for Metastatic Breast Cancer Therapy.

    abstract::The unsatisfied results of cancer therapy are caused by many issues and metastasis of cancer cells is one of the major challenge. It has been reported that inhibiting the SDF1/CXCR4 interaction can significantly reduce the metastasis of breast cancer cells to regional lymph nodes and lung. Herein, a nanogel system equ...

    journal_title:Biomacromolecules

    pub_type: 杂志文章

    doi:10.1021/acs.biomac.7b00208

    authors: Zhang F,Gong S,Wu J,Li H,Oupicky D,Sun M

    更新日期:2017-06-12 00:00:00

  • Viscoelastic behavior of cellulose acetate in a mixed solvent system.

    abstract::The effect of increasing water composition on the rheological and microstructural behavior of a ternary cellulose acetate (CA)/N,N-dimethylacetamide (DMA)/water system is examined. Addition of water to the CA/DMA system results in enhanced steady shear viscosity and dynamic viscoelastic properties and ultimately to ph...

    journal_title:Biomacromolecules

    pub_type: 杂志文章

    doi:10.1021/bm0611681

    authors: Appaw C,Gilbert RD,Khan SA,Kadla JF

    更新日期:2007-05-01 00:00:00

  • Triblock Copolymer Nanovesicles for pH-Responsive Targeted Delivery and Controlled Release of siRNA to Cancer Cells.

    abstract::New pH-responsive polymersomes for active anticancer oligonucleotide delivery were prepared from triblock copolymers. The delivery systems were formed by two terminal hydrophilic blocks, PEG and polyglycerolmethacrylate (poly-GMA), and a central weakly basic block, polyimidazole-hexyl methacrylate (poly-ImHeMA), which...

    journal_title:Biomacromolecules

    pub_type: 杂志文章

    doi:10.1021/acs.biomac.5b00286

    authors: Gallon E,Matini T,Sasso L,Mantovani G,Armiñan de Benito A,Sanchis J,Caliceti P,Alexander C,Vicent MJ,Salmaso S

    更新日期:2015-07-13 00:00:00

  • Synthesis and characterization of biocompatible thermo-responsive gelators based on ABA triblock copolymers.

    abstract::The synthesis of biocompatible, thermo-responsive ABA triblock copolymers in which the outer A blocks comprise poly(N-isopropylacrylamide) and the central B block is poly(2-methacryloyloxyethyl phosphorylcholine) is achieved using atom transfer radical polymerization with a commercially available bifunctional initiato...

    journal_title:Biomacromolecules

    pub_type: 杂志文章

    doi:10.1021/bm049331k

    authors: Li C,Tang Y,Armes SP,Morris CJ,Rose SF,Lloyd AW,Lewis AL

    更新日期:2005-03-01 00:00:00

  • Analytical model study of dendrimer/DNA complexes.

    abstract::The interaction between positively charged poly(amido amine) (PAMAM) dendrimers of generation 4 and DNA has been investigated for two DNA lengths; 2000 basepairs (bp; L = 680 nm) and 4331 bp (L = 1472.5 nm) using a theoretical model by Schiessel for a semiflexible polyelectrolyte and hard spheres. The model was modifi...

    journal_title:Biomacromolecules

    pub_type: 杂志文章

    doi:10.1021/bm9000662

    authors: Qamhieh K,Nylander T,Ainalem ML

    更新日期:2009-07-13 00:00:00

  • Preventing protein adsorption from a range of surfaces using an aqueous fish protein extract.

    abstract::We utilize an aqueous extract of fish proteins (FPs) as a coating for minimizing the adsorption of fibrinogen (Fg) and human serum albumin (HSA). The surfaces include stainless steel (SS), gold (Au), silicon dioxide (SiO(2)), and poly(styrene) (PS). The adsorption processes (kinetics and adsorbed mass) are followed by...

    journal_title:Biomacromolecules

    pub_type: 杂志文章

    doi:10.1021/bm900589r

    authors: Pillai S,Arpanaei A,Meyer RL,Birkedal V,Gram L,Besenbacher F,Kingshott P

    更新日期:2009-10-12 00:00:00

  • Role of (1,3)(1,4)-β-glucan in cell walls: interaction with cellulose.

    abstract::(1,3)(1,4)-β-D-Glucan (mixed-linkage glucan or MLG), a characteristic hemicellulose in primary cell walls of grasses, was investigated to determine both its role in cell walls and its interaction with cellulose and other cell wall polysaccharides in vitro. Binding isotherms showed that MLG adsorption onto microcrystal...

    journal_title:Biomacromolecules

    pub_type: 杂志文章

    doi:10.1021/bm5001247

    authors: Kiemle SN,Zhang X,Esker AR,Toriz G,Gatenholm P,Cosgrove DJ

    更新日期:2014-05-12 00:00:00

  • Synthesis of various glycopolymer architectures via RAFT polymerization: from block copolymers to stars.

    abstract::Well-defined linear poly(acryloyl glucosamine) (PAGA) exhibiting molar masses ranging from 3 to 120 K and low polydispersities have been prepared via reversible addition-fragmentation chain transfer polymerization (RAFT) in aqueous solution without recourse to protecting group chemistry. The livingness of the process ...

    journal_title:Biomacromolecules

    pub_type: 杂志文章

    doi:10.1021/bm0506086

    authors: Bernard J,Hao X,Davis TP,Barner-Kowollik C,Stenzel MH

    更新日期:2006-01-01 00:00:00

  • Ultrafast SET-LRP with Peptoid Cytostatic Drugs as Monofunctional and Bifunctional Initiators.

    abstract::To continue expanding the use of Single Electron Transfer-Living Radical Polymerization (SET-LRP) in applications at the interface between macromolecular science, biomacromolecules, biology and medicine, it is essential to develop novel initiators that do not compromise the structural stability of synthesized polymers...

    journal_title:Biomacromolecules

    pub_type: 杂志文章

    doi:10.1021/acs.biomac.7b00722

    authors: Lligadas G,Enayati M,Grama S,Smail R,Sherman SE,Percec V

    更新日期:2017-08-14 00:00:00

  • Post-Thaw Culture and Measurement of Total Cell Recovery Is Crucial in the Evaluation of New Macromolecular Cryoprotectants.

    abstract::The storage and transport of cells is a fundamental technology which underpins cell biology, biomaterials research, and emerging cell-based therapies. Inspired by antifreeze and ice-binding proteins in extremophiles, macromolecular (polymer) cryoprotectants are emerging as exciting biomaterials to enable the reduction...

    journal_title:Biomacromolecules

    pub_type: 杂志文章

    doi:10.1021/acs.biomac.0c00591

    authors: Murray KA,Gibson MI

    更新日期:2020-07-13 00:00:00

  • Esterase-Responsive Polypeptide Vesicles as Fast-Response and Sustained-Release Nanocompartments for Fibroblast-Exempt Drug Delivery.

    abstract::Enzyme-responsive polypeptide vesicles have attracted considerable attention for precision theranostics because of their biocompatibility, biodegradability, and unique secondary conformation transition triggered by the catalytic actions of enzymes. These promising potentials of polypeptide vesicles could be limited in...

    journal_title:Biomacromolecules

    pub_type: 杂志文章

    doi:10.1021/acs.biomac.0c01251

    authors: Duan W,Ji S,Guan Y,Mu X,Fang S,Lu Y,Zhou X,Sun J,Li Z

    更新日期:2020-12-14 00:00:00

  • Swelling behavior and morphological evolution of mixed gelatin/silk fibroin hydrogels.

    abstract::Mixed protein-based hydrogels have been prepared by blending gelatin (G) with amorphous Bombyx mori silk fibroin (SF) and promoting beta-crystallization of SF via subsequent exposure to methanol or methanol/water solutions. The introduction of beta crystals in SF serves to stabilize the hydrogel network and extend the...

    journal_title:Biomacromolecules

    pub_type: 杂志文章

    doi:10.1021/bm050396c

    authors: Gil ES,Frankowski DJ,Spontak RJ,Hudson SM

    更新日期:2005-11-01 00:00:00