Abstract:
:Exudates from Streptomyces griseoflavus Tü 2484 effectively mediated electron transfer between hydrogen sulfide and various nitrobenzenes. In general, pseudo-first-order kinetics were observed, except for the initial phase of the reaction at higher pH values. Under fixed pH and Dh conditions, linear free energy relationships were found between the logarithms of the reaction rate constants and the one-electron reduction potentials of the nitroaromatic compounds. No competition was observed between various compounds. Comparison of the results of this study with the results of experiments conducted with model quinones and an iron porphyrin suggest that the secondary metabolites cinnaquinone and dicinnaquinone, excreted by strain Tü 2484 on the order of 100 mg/liter, are responsible for the catalytic activity of the exudate. Further support for this hypothesis comes from the facts that the catalytic activity of the exudate became prominent only after the growth phase of the microorganisms and that the mediating substances have a molecular weight of less than 3,000.
journal_name
Appl Environ Microbioljournal_title
Applied and environmental microbiologyauthors
Glaus MA,Heijman CG,Schwarzenbach RP,Zeyer Jdoi
10.1128/AEM.58.6.1945-1951.1992keywords:
subject
Has Abstractpub_date
1992-06-01 00:00:00pages
1945-51issue
6eissn
0099-2240issn
1098-5336journal_volume
58pub_type
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journal_title:Applied and environmental microbiology
pub_type: 杂志文章
doi:10.1128/AEM.52.6.1299-1304.1986
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journal_title:Applied and environmental microbiology
pub_type: 杂志文章
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journal_title:Applied and environmental microbiology
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pub_type: 杂志文章
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doi:10.1128/AEM.61.11.3967-3971.1995
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journal_title:Applied and environmental microbiology
pub_type: 杂志文章
doi:10.1128/AEM.45.6.1808-1815.1983
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journal_title:Applied and environmental microbiology
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doi:10.1128/AEM.43.2.371-377.1982
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journal_title:Applied and environmental microbiology
pub_type: 杂志文章
doi:10.1128/AEM.38.2.311-313.1979
更新日期:1979-08-01 00:00:00
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更新日期:2012-10-01 00:00:00
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pub_type: 杂志文章
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更新日期:2005-12-01 00:00:00
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journal_title:Applied and environmental microbiology
pub_type: 杂志文章
doi:10.1128/AEM.61.3.1150-1152.1995
更新日期:1995-03-01 00:00:00
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journal_title:Applied and environmental microbiology
pub_type: 杂志文章
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更新日期:1994-10-01 00:00:00
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journal_title:Applied and environmental microbiology
pub_type: 杂志文章
doi:10.1128/AEM.59.3.860-866.1993
更新日期:1993-03-01 00:00:00
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journal_title:Applied and environmental microbiology
pub_type: 杂志文章
doi:10.1128/AEM.48.6.1208-1213.1984
更新日期:1984-12-01 00:00:00
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journal_title:Applied and environmental microbiology
pub_type: 杂志文章
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更新日期:2002-12-01 00:00:00
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journal_title:Applied and environmental microbiology
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更新日期:2005-09-01 00:00:00
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journal_title:Applied and environmental microbiology
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更新日期:1986-12-01 00:00:00
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journal_title:Applied and environmental microbiology
pub_type: 杂志文章
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更新日期:2002-02-01 00:00:00
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journal_title:Applied and environmental microbiology
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更新日期:2014-12-01 00:00:00
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journal_title:Applied and environmental microbiology
pub_type: 杂志文章
doi:10.1128/AEM.47.4.768-774.1984
更新日期:1984-04-01 00:00:00
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journal_title:Applied and environmental microbiology
pub_type: 杂志文章
doi:
更新日期:1989-06-01 00:00:00
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journal_title:Applied and environmental microbiology
pub_type: 杂志文章
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更新日期:2008-04-01 00:00:00