Abstract:
:Benzoxazinoids are secondary metabolites of grasses that function as natural pesticides. While many steps of DIMBOA biosynthesis have been elucidated, the mechanism of the introduction of OCH(3)-group at the C-7 position was unknown. Inhibitor experiments in Triticum aestivum and Zea mays suggest that a 2-oxoglutarate-dependent dioxygenase catalyses the hydroxylation reaction at C-7. Cloning and reverse genetics analysis have identified the Bx6 gene that encodes this enzyme. Bx6 is located in the Bx-gene cluster of maize.
journal_name
Phytochemistryjournal_title
Phytochemistryauthors
Frey M,Huber K,Park WJ,Sicker D,Lindberg P,Meeley RB,Simmons CR,Yalpani N,Gierl Adoi
10.1016/s0031-9422(02)00556-3subject
Has Abstractpub_date
2003-02-01 00:00:00pages
371-6issue
3eissn
0031-9422issn
1873-3700pii
S0031942202005563journal_volume
62pub_type
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