Abstract:
:The full assignments of the (1)H and (13)C NMR signals of steroids bearing the 16beta,23:23,26-diepoxy side chain are provided. Differentiation of the diasterotopic H-26 pair was achieved with the aid of NOESY experiments. The main substituent and steric effects associated with this moiety and their influence on the chemical shifts of the neighboring atoms are discussed.
journal_name
Steroidsjournal_title
Steroidsauthors
Vázquez-Ramírez I,Macías-Alonso M,Arcos-Ramos RO,Ruíz-Pérez KM,Solano-Ramírez DO,Iglesias Arteaga MAdoi
10.1016/j.steroids.2008.01.027subject
Has Abstractpub_date
2008-07-01 00:00:00pages
642-51issue
6eissn
0039-128Xissn
1878-5867pii
S0039-128X(08)00052-4journal_volume
73pub_type
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