Decisive role of vacuum-assisted carbonization in valorization of lignin-enriched (Juglans regia-shell) biowaste.

Abstract:

:Bioenergy is considered a sustainable substitute to fossil-fuel resources and the development of a prudent combination of renewable and innovative conversion technologies are essential for the valorization and effective conversion of biowaste to value-added commodities. Here, a negative pressure-induced carbonization process was proposed for the valorization of lignin-enriched biowaste precursor to bio-oil and environmental materials (biochar) at various temperatures. The high heating values (HHV) of the as-prepared biochars from the lignin enriched precursor under negative pressure (low-medium vacuum) were within 25.9-31.5 MJ/kg, which matched satisfactorily to the commercial charcoal. Whereas, the bio-oils produced from the lignin enriched precursor under vacuum conditions was a blend of complex aromatic and straight-chain hydro-carbons, including aldehyde, ketone, phenol, and furans, exhibiting ability as potential heating-oil with HHV within 21.2-28.2 MJ/kg. Moreover, the biochars produced under vacuum environments at higher temperature showed greater stability (22.5-35.9%) than those produced under N2 atmosphere.

journal_name

Bioresour Technol

journal_title

Bioresource technology

authors

Yousaf B,Liu G,Ubaid Ali M,Abbas Q,Liu Y,Ullah H,Imtiyaz Cheema A

doi

10.1016/j.biortech.2020.124541

subject

Has Abstract

pub_date

2020-12-14 00:00:00

pages

124541

eissn

0960-8524

issn

1873-2976

pii

S0960-8524(20)31815-0

journal_volume

323

pub_type

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