Facile synthesis of xanthan biopolymer integrated 3D hierarchical graphene oxide/titanium dioxide composite for adsorptive lead removal in wastewater.

Abstract:

:Xanthan integrated graphene oxide functionalized by titanium dioxide was successfully prepared through facile, eco-friendly and cost effective ice-templating technique. The three-dimensional (3D) graphene composite demonstrated relatively high temperature stability, chemical functionalities and porous sponge-like structure. The adsorption of lead was favored by high initial concentration and shaking speed at the operational solution pH. The process equilibrium and kinetic adhered to the Langmuir and pseudo-second-order correlations, respectively. The biomass integrated graphene composite showed maximum adsorption capacities ranging from 132.18 to 199.22 mg/g for 30-70 °C. Moreover, it was highly regenerable under mild conditions (0.1 M hydrochloric acid, 30 °C) and used repeatedly while retaining 84.78% of its initial adsorption capacity at the fifth adsorption-regeneration cycle. With comparatively high lead adsorption capacities, adequate recyclability and environmentally friendliness, the as-prepared 3D graphene composite has high application potential in heavy metal-wastewater separation for protection of the environment and human health.

journal_name

Bioresour Technol

journal_title

Bioresource technology

authors

Lai KC,Lee LY,Hiew BYZ,Thangalazhy-Gopakumar S,Gan S

doi

10.1016/j.biortech.2020.123296

subject

Has Abstract

pub_date

2020-08-01 00:00:00

pages

123296

eissn

0960-8524

issn

1873-2976

pii

S0960-8524(20)30568-X

journal_volume

309

pub_type

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