Biotreatment of acidic zinc- and copper-containing wastewater using ethanol-fed sulfidogenic anaerobic baffled reactor.

Abstract:

:The treatment of acidic (pH 6.5-3), sulfate- (2-3 g/L), Zn- and Cu- (total metal 0-500 mg/L) containing wastewater was studied in a four-stage anaerobic baffled reactor (ABR) at 35 °C for 250 days. Ethanol was supplemented (COD/SO4(2-) = 0.67) as carbon and electron source for sulfate reducing bacteria. Sulfate reduction, COD oxidation and metal precipitation efficiencies were 70-92, 80-94 and >99%, respectively. The alkalinity produced from sulfidogenic ethanol oxidation increased the wastewater pH from 3.0 to 7.0-8.0. The electron flow from organic oxidation to sulfate averaged 87%. Decreasing feed pH to 3 and increasing total metal concentrations to 500 mg/L did not adversely affect the performance of ABR and sufficient alkalinity was produced to increase the effluent pH to neutral values. More than 99% of metals were precipitated in the form of metal-sulfides. Accumulation of precipitated metals in the first compartment allowed metal recovery without disturbing reactor performance seriously.

journal_name

Bioprocess Biosyst Eng

authors

Sahinkaya E,Yucesoy Z

doi

10.1007/s00449-010-0423-9

subject

Has Abstract

pub_date

2010-10-01 00:00:00

pages

989-97

issue

8

eissn

1615-7591

issn

1615-7605

journal_volume

33

pub_type

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