Abstract:
:This study evaluates the use of engineered biochar as a heterogeneous solid acid catalyst for transesterification of algal oil derived from a native microalgal consortium. Biochar derived from sugarcane bagasse, coconut shell, corncob and peanut shell were evaluated for catalytic activity following surface modification. Peanut shell pyrolyzed at 400 °C with the sulfonic acid density of 0.837 mmol/g having 6.616 m2/g surface area was selected for efficient catalysis. The efficiency of transesterification was evaluated with 1-7 wt% catalyst loading, methanol: oil ratio of 6:1 to 30:1 at 55-85 °C over 2-8 h. Biodiesel yield of 94.91% was obtained with 5 wt% catalyst loading, MeOH: oil ratio of 20:1 at 65 °C after 4 h. Spectral analysis of algal biodiesel showed the presence of functional groups corresponding to esters. GC-MS analysis revealed the prominent presence of palmitic and oleic acids, further advocating the suitability of the technology for commercial application.
journal_name
Bioresour Technoljournal_title
Bioresource technologyauthors
Behera B,Selvam S M,Dey B,Balasubramanian Pdoi
10.1016/j.biortech.2020.123392subject
Has Abstractpub_date
2020-08-01 00:00:00pages
123392eissn
0960-8524issn
1873-2976pii
S0960-8524(20)30664-7journal_volume
310pub_type
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