Abstract:
:In addition to their conventional uses, metal-organic frameworks (MOFs) have recently emerged as an interesting class of functional materials and precursors of inorganic materials for electrochemical energy storage and conversion technologies. This class of MOF-related materials can be broadly categorized into two groups: pristine MOF-based materials and MOF-derived functional materials. Although the diversity in composition and structure leads to diverse and tunable functionalities of MOF-based materials, it appears that much more effort in this emerging field is devoted to synthesizing MOF-derived materials for electrochemical applications. This is in view of two main drawbacks of MOF-based materials: the low conductivity nature and the stability issue. On the contrary, MOF-derived synthesis strategies have substantial advantages in controlling the composition and structure of MOF-derived materials. From this perspective, we review some emerging applications of both groups of MOF-related materials as electrode materials for rechargeable batteries and electrochemical capacitors, efficient electrocatalysts, and even electrolytes for electrochemical devices. By highlighting the advantages and challenges of each class of materials for different applications, we hope to shed some light on the future development of this highly exciting area.
journal_name
Sci Advjournal_title
Science advancesauthors
Wu HB,Lou XWDdoi
10.1126/sciadv.aap9252subject
Has Abstractpub_date
2017-12-01 00:00:00pages
eaap9252issue
12issn
2375-2548pii
aap9252journal_volume
3pub_type
杂志文章,评审相关文献
Science Advances文献大全abstract::Asymmetric interactions such as entropic (e.g., encoded by nonspherical shapes) or surface forces (e.g., encoded by patterned surface chemistry or DNA hybridization) provide access to functional states of colloidal matter, but versatile approaches for engineering asymmetric van der Waals interactions have the potentia...
journal_title:Science advances
pub_type: 杂志文章
doi:10.1126/sciadv.abb1327
更新日期:2020-06-19 00:00:00
abstract::Transcription factors control gene expression in all life. This raises the question of what is the smallest protein that can support such activity. In nature, Cro from bacteriophage λ is one of the smallest known repressors (66 amino acids), and activators are typically much larger (e.g., λ cI, 237 amino acids). Previ...
journal_title:Science advances
pub_type: 杂志文章
doi:10.1126/sciadv.aba2728
更新日期:2020-06-10 00:00:00
abstract::Characterizing and understanding the emergence of multiple macroscopically ordered electronic phases through subtle tuning of temperature, pressure, and chemical doping has been a long-standing central issue for complex materials research. We report the first comprehensive studies of optical doping-induced emergence o...
journal_title:Science advances
pub_type: 杂志文章
doi:10.1126/sciadv.1400173
更新日期:2015-06-26 00:00:00
abstract::The essence of turbulent flow is the conveyance of energy through the formation, interaction, and destruction of eddies over a wide range of spatial scales-from the largest scales where energy is injected down to the smallest scales where it is dissipated through viscosity. Currently, there is no mechanistic framework...
journal_title:Science advances
pub_type: 杂志文章
doi:10.1126/sciadv.aaz2717
更新日期:2020-02-28 00:00:00
abstract::Porous membranes with ultrafast ion permeation and high ion selectivity are highly desirable for efficient mineral separation, water purification, and energy conversion, but it is still a huge challenge to efficiently separate monatomic ions of the same valence and similar sizes using synthetic membranes. We report me...
journal_title:Science advances
pub_type: 杂志文章
doi:10.1126/sciadv.aaq0066
更新日期:2018-02-09 00:00:00
abstract::The repair of DNA double-strand breaks occurs through nonhomologous end joining or homologous recombination in vertebrate cells-a choice that is thought to be decided by a competition between DNA-dependent protein kinase (DNA-PK) and the Mre11/Rad50/Nbs1 (MRN) complex but is not well understood. Using ensemble biochem...
journal_title:Science advances
pub_type: 杂志文章
doi:10.1126/sciadv.aay0922
更新日期:2020-01-08 00:00:00
abstract::Strong coupling between a cavity and transition dipole moments in emitters leads to vacuum Rabi splitting. Researchers have not reported strong coupling between a single emitter and a dielectric cavity at room temperature until now. In this study, we investigated the photoluminescence (PL) spectra of colloidal quantum...
journal_title:Science advances
pub_type: 杂志文章
doi:10.1126/sciadv.abb3095
更新日期:2020-11-20 00:00:00
abstract::Rising temperatures in the Arctic Ocean region are responsible for changes such as reduced ice cover, permafrost thawing, and increased river discharge, which, together, alter nutrient and carbon cycles over the vast Arctic continental shelf. We show that the concentration of radium-228, sourced to seawater through se...
journal_title:Science advances
pub_type: 杂志文章
doi:10.1126/sciadv.aao1302
更新日期:2018-01-03 00:00:00
abstract::The basic physics of earthquakes is such that strong ground motion cannot be expected from an earthquake unless the earthquake itself is very close or has grown to be very large. We use simple seismological relationships to calculate the minimum time that must elapse before such ground motion can be expected at a dist...
journal_title:Science advances
pub_type: 杂志文章
doi:10.1126/sciadv.aaq0504
更新日期:2018-03-21 00:00:00
abstract::Active materials are capable of converting free energy into directional motion, giving rise to notable dynamical phenomena. Developing a general understanding of their structure in relation to the underlying nonequilibrium physics would provide a route toward control of their dynamic behavior and pave the way for pote...
journal_title:Science advances
pub_type: 杂志文章
doi:10.1126/sciadv.aat7779
更新日期:2018-10-12 00:00:00
abstract::Unraveling the genetic and epigenetic determinants of phenotypes is critical for understanding and re-engineering biology and would benefit from improved methods to separate cells based on phenotypes. Here, we report SPOTlight, a versatile high-throughput technique to isolate individual yeast or human cells with uniqu...
journal_title:Science advances
pub_type: 杂志文章
doi:10.1126/sciadv.abb7438
更新日期:2020-10-23 00:00:00
abstract::Engineering the thermal conductivity of amorphous materials is highly essential for the thermal management of future electronic devices. Here, we demonstrate the impact of ultrafine nanostructuring on the thermal conductivity reduction of amorphous silicon nitride (a-Si3N4) thin films, in which the thermal transport i...
journal_title:Science advances
pub_type: 杂志文章
doi:10.1126/sciadv.abc0075
更新日期:2020-09-25 00:00:00
abstract::Massive declines in population abundances of marine animals have been documented over century-long time scales. However, analogous loss of spatial extent of habitat-forming organisms is less well known because georeferenced data are rare over long time scales, particularly in subtidal, tropical marine regions. We use ...
journal_title:Science advances
pub_type: 杂志文章
doi:10.1126/sciadv.1603155
更新日期:2017-09-06 00:00:00
abstract::Telomerase is a ribonucleoprotein complex that catalyzes addition of telomeric DNA repeats to maintain telomeres in replicating cells. Here, we demonstrate that the telomerase protein hTERT performs an additional role at telomeres that is independent of telomerase catalytic activity yet essential for telomere integrit...
journal_title:Science advances
pub_type: 杂志文章
doi:10.1126/sciadv.aav4409
更新日期:2019-10-02 00:00:00
abstract::Transplantation with donor corneas is the mainstay for treating corneal blindness, but a severe worldwide shortage necessitates the development of other treatment options. Corneal perforation from infection or inflammation is sealed with cyanoacrylate glue. However, the resulting cytotoxicity requires transplantation....
journal_title:Science advances
pub_type: 杂志文章
doi:10.1126/sciadv.aba2187
更新日期:2020-06-17 00:00:00
abstract::Despite the potential of photodynamic therapy (PDT), its comprehensive use in cancer treatment has not been achieved because of the nondegradable risks of photosensitizing drugs and limits of light penetration and instrumentation. Here, we present bioluminescence (BL)-induced proteinaceous PDT (BLiP-PDT), through the ...
journal_title:Science advances
pub_type: 杂志文章
doi:10.1126/sciadv.aba3009
更新日期:2020-09-11 00:00:00
abstract::G-quadruplex (G4) is one of the most important secondary structures in nucleic acids. Until recently, G4 RNAs have not been reported in any ribovirus, such as the hepatitis C virus. Our bioinformatics analysis reveals highly conserved guanine-rich consensus sequences within the core gene of hepatitis C despite the hig...
journal_title:Science advances
pub_type: 杂志文章
doi:10.1126/sciadv.1501535
更新日期:2016-04-01 00:00:00
abstract::The accelerating global spread of arboviruses, such as Zika virus (ZIKV), highlights the need for more proactive mosquito surveillance. However, a major challenge during arbovirus outbreaks has been the lack of rapid and affordable tests for pathogen detection in mosquitoes. We show for the first time that near-infrar...
journal_title:Science advances
pub_type: 杂志文章
doi:10.1126/sciadv.aat0496
更新日期:2018-05-23 00:00:00
abstract::Wearable sweat analysis devices for monitoring of multiple health-related biomarkers with high sensitivity are highly desired for noninvasive and real-time monitoring of human health. Here, we report a flexible sweat analysis patch based on a silk fabric-derived carbon textile for simultaneous detection of six health-...
journal_title:Science advances
pub_type: 杂志文章
doi:10.1126/sciadv.aax0649
更新日期:2019-11-08 00:00:00
abstract::[This corrects the article DOI: 10.1126/sciadv.aao6652.]. ...
journal_title:Science advances
pub_type: 杂志文章,已发布勘误
doi:10.1126/sciadv.aau4932
更新日期:2018-07-13 00:00:00
abstract::Detection of amyloid-β (Aβ) aggregates contributes to the diagnosis of Alzheimer disease (AD). Plasma Aβ is deemed a less invasive and more accessible hallmark of AD, as Aβ can penetrate blood-brain barriers. However, correlations between biofluidic Aβ concentrations and AD progression has been tenuous. Here, we intro...
journal_title:Science advances
pub_type: 杂志文章
doi:10.1126/sciadv.aav1388
更新日期:2019-04-17 00:00:00
abstract::Carbon deposits are well-known inhibitors of transition metal catalysts. In contrast to this undesirable behavior, here we show that epitaxial graphene grown on Ru(0001) promotes the reversible formation of a C-C bond between -CH2CN and 7,7,8,8-tetracyano-p-quinodimethane (TCNQ). The catalytic role of graphene is mult...
journal_title:Science advances
pub_type: 杂志文章
doi:10.1126/sciadv.aau9366
更新日期:2018-12-14 00:00:00
abstract::We report a dual-mode organic photodetector (OPD) that has a trilayer visible light absorber/optical spacer/near-infrared (NIR) light absorber configuration. In the presence of NIR light, photocurrent is produced in the NIR light-absorbing layer due to the trap-assisted charge injection at the organic/cathode interfac...
journal_title:Science advances
pub_type: 杂志文章
doi:10.1126/sciadv.aaw8065
更新日期:2020-01-31 00:00:00
abstract::Diets rich in sugar, salt, and fat alter taste perception and food preference, contributing to obesity and metabolic disorders, but the molecular mechanisms through which this occurs are unknown. Here, we show that in response to a high sugar diet, the epigenetic regulator Polycomb Repressive Complex 2.1 (PRC2.1) pers...
journal_title:Science advances
pub_type: 杂志文章
doi:10.1126/sciadv.abc8492
更新日期:2020-11-11 00:00:00
abstract::Mineralization is the most fundamental process in vertebrates. It is predominantly mediated by osteoblasts, which secrete mineral precursors, most likely through matrix vesicles (MVs). These vesicular structures are calcium and phosphate rich and contain organic material such as acidic proteins. However, it remains la...
journal_title:Science advances
pub_type: 杂志文章
doi:10.1126/sciadv.aax0672
更新日期:2019-07-03 00:00:00
abstract::Nucleosynthetic isotope variability among solar system objects provides insights into the accretion history of terrestrial planets. We report on the nucleosynthetic Fe isotope composition (μ54Fe) of various meteorites and show that the only material matching the terrestrial composition is CI (Ivuna-type) carbonaceous ...
journal_title:Science advances
pub_type: 杂志文章
doi:10.1126/sciadv.aay7604
更新日期:2020-02-12 00:00:00
abstract::Oxygen activation is a critical step in ubiquitous heterogeneous oxidative processes, most prominently in catalysis, electrolysis, and pharmaceutical applications. We present here our findings on metal-free O2 activation on covalent triazine frameworks (CTFs) as an important class of N-rich materials. The O2 activatio...
journal_title:Science advances
pub_type: 杂志文章
doi:10.1126/sciadv.aaz2310
更新日期:2020-04-03 00:00:00
abstract::Avian wing shape is highly variable across species but only coarsely associated with flight behavior, performance, and body mass. An underexplored but potentially explanatory feature is the ability of birds to actively change wing shape to meet aerodynamic and behavioral demands. Across 61 species, we found strong ass...
journal_title:Science advances
pub_type: 杂志文章
doi:10.1126/sciadv.aaw6670
更新日期:2019-10-23 00:00:00
abstract::Oncogenic RAS mutant (RASMUT) proteins have been considered undruggable via conventional antibody regimens owing to the intracellular location restricting conventional-antibody accessibility. Here, we report a pan-RAS-targeting IgG antibody, inRas37, which directly targets the intracellularly activated form of various...
journal_title:Science advances
pub_type: 杂志文章
doi:10.1126/sciadv.aay2174
更新日期:2020-01-15 00:00:00
abstract::Glass-forming ability (GFA) is the ability of a liquid to avoid crystallization during cooling. Metal-organic frameworks (MOFs) are a new class of glass formers (1-3), with hitherto unknown dynamic and thermodynamic properties. We report the discovery of a new series of tetrahedral glass systems, zeolitic imidazolate ...
journal_title:Science advances
pub_type: 杂志文章
doi:10.1126/sciadv.aao6827
更新日期:2018-03-09 00:00:00