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Aqueous vanadium ion dynamics relevant to bioinorganic chemistry: A review.

Abstract：

:Aqueous solutions of the four highest vanadium oxidation states exhibit four diverse colors, which only hint at the diverse reactions that these ions can undergo. Cationic vanadium ions form complexes with ligands; anionic vanadium ions form complexes with ligands and self-react to form isopolyanions. All vanadium species undergo oxidation-reduction reactions. With a few exceptions, elucidation of the dynamics of these reactions awaited the development of fast reaction techniques before the kinetics of elementary ligation, condensation, reduction, and oxidation of the aqueous vanadium ions could be investigated. As the biological roles played by endogenous and therapeutic vanadium expand, it is appropriate to bring the results of the diverse kinetics studies under one umbrella. To achieve this goal this review presents a systematic examination of elementary aqueous vanadium ion dynamics.

journal_name

J Inorg Biochem

journal_title

Journal of inorganic biochemistry

authors

Kustin K

doi

10.1016/j.jinorgbio.2014.12.009

subject

Has Abstract

pub_date

2015-06-01 00:00:00

pages

32-8

eissn

0162-0134

issn

1873-3344

pii

S0162-0134(14)00302-X

journal_volume

147

pub_type

杂志文章,评审

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